methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

Base Information

Chemical Name:methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate
CAS No.:224044-69-3
Molecular Formula:C₂₅H₃₁NO₁₃
Molecular Weight:553.52
Hs Code.:

Synonyms:methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

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Technology Process of methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

There total 10 articles about methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 289665-42-5
3-(4-methoxy-4-oxobutanoyl)-2-nitrophenyl tetra-O-acetyl-β-D-glucopyranoside

: 224044-69-3
methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; at 20 ℃; for 3h;
DOI:10.1016/S0040-4020(00)00285-4

Reference yield: 63.0%

: 224044-68-2
methyl (E)-4-oxo-4-<2-nitro-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

: 224044-69-3
methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

Guidance literature:: With hydrogen; platinum(IV) oxide; In ethanol; ethyl acetate; for 12h; under 760 Torr;
DOI:10.1021/jo982321n

Reference yield:

: 93367-77-2,224044-66-0
(E)-4-(3-hydroxy-2-nitrophenyl)-4-oxobut-2-enoic acid

: 224044-69-3
methyl 4-oxo-4-<2-amino-3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)oxyphenyl>-2-butenoate

Guidance literature:: Multi-step reaction with 3 steps

1: 45 percent / DCC / CH₂Cl₂ / Ambient temperature

2: 61 percent / Hg(CN)2, K₂CO₃ / acetonitrile / 4 h / Ambient temperature

3: 63 percent / H₂ / PtO₂ / ethanol; ethyl acetate / 12 h / 760 Torr

With hydrogen; mercury(II) cyanide; potassium carbonate; dicyclohexyl-carbodiimide; platinum(IV) oxide; In ethanol; dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1021/jo982321n