O₂NC₆H₄SC(O)C(CH(CH₃)2)CH₂

Base Information

• Chemical Name: O₂NC₆H₄SC(O)C(CH(CH₃)2)CH₂
• CAS No.: 893445-29-9
• Molecular Formula: C₁₂H₁₃NO₃S
• Molecular Weight: 251.306
• Mol file: 893445-29-9.mol

Synonyms:O₂NC₆H₄SC(O)C(CH(CH₃)2)CH₂

Chemical Property of O₂NC₆H₄SC(O)C(CH(CH₃)2)CH₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of O₂NC₆H₄SC(O)C(CH(CH₃)2)CH₂

There total 1 articles about O₂NC₆H₄SC(O)C(CH(CH₃)2)CH₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-methyl-2-methylenebutanoyl chloride (72846-28-7) + para-nitrobenzenethiol (1849-36-1) → O2NC6H4SC(O)C(CH(CH3)2)CH2 (893445-29-9)

Guidance literature:

With pyridine; In tetrahydrofuran;

DOI:10.1021/ol800754w

Reference yield: 60.0%

O2NC6H4SC(O)C(CH(CH3)2)CH2 (893445-29-9) + 2-methyl-but-3-yn-2-ol (115-19-5) → 2,3-dihydro-3-isopropyl-6-(dimethyl(p-nitrophenoxy)methyl)-thiopyran-4-one (1033042-05-5)

Guidance literature:

With copper(l) iodide; potassium carbonate; triethylamine; palladium dichloride; In N,N-dimethyl-formamide; at 80 ℃; for 6h; Inert atmosphere;

DOI:10.1021/ol800754w

Reference yield:

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + O2NC6H4SC(O)C(CH(CH3)2)CH2 (893445-29-9) → trans-[Pt(SC6H4NO2-p)(PPh3)2(C(O)C(i-Pr)=CH2)] (895133-30-9,893445-57-3)

Guidance literature:

In benzene-d6; Pt complex, thioester and C6D6 were added into NMR tube under N2; kept at 25°C; NMR monitoring; not isolated; Kinetics;

DOI:10.1021/om050834w

upstream raw materials:

3-methyl-2-methylenebutanoyl chloride

para-nitrobenzenethiol

Downstream raw materials:

cis-[Pt(SC₆H₄NO₂-p)(PPh₃)2(C(O)C(Me)=CH₂)]

trans-[Pt(SC₆H₄NO₂-p)(PPh₃)2(C(O)C(i-Pr)=CH₂)]

2,3-dihydro-3-isopropyl-6-(dimethyl(p-nitrophenoxy)methyl)-thiopyran-4-one