tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

Base Information

Chemical Name:tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate
CAS No.:862075-55-6
Molecular Formula:C₃₄H₂₃N₂O₅PRe*F₆P
Molecular Weight:901.712
Hs Code.:

Synonyms:tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

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Chemical Property of tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

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Technology Process of tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

There total 1 articles about tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 395062-54-1
tricarbonyl(acetonitrile)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

: 2129-31-9
4-diphenylphosphanobenzoic acid

: 862075-55-6
tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

Guidance literature:: In acetone; metal compd. and ligand (1:1.5 molar ratio); under N2, refluxed in dark overnight, evapd., treated (CH2Cl2), pptd., filtered off, washed (CH2Cl2), dried (vac.), elem. anal.;
DOI:10.1021/ja0510360

Reference yield: 74.0%

: 862075-55-6
tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

: 15100-75-1,75898-47-4
L-phenylalanine tert-butyl ester hydrochloride

: [Re(CO)3((C₆H₅)2PC₆H₄CONHCH(CH₂C₆H₅)COOH)(C₁₂H₈N₂)]⁽¹⁺⁾*PF₆^(1-)=[Re(CO)3((C₆H₅)2PC₆H₄CONHCH(C₇H₇)COOH)(C₁₂H₈N₂)][PF₆]

Guidance literature:: With WSC*HCl; 1-hydroxybenzotriazole; N-methylmorpholine; In dichloromethane; 1:1 mixt. of metal compd. and ligand mixed with WSC*HCl (1.1 equiv.) andHOBt (1.1 equiv.), N-methylmorpholine (4 equiv. added); stirred overnight, evapd., dissolved (CH2Cl2), washed (water), org. layer dried (MgSO4), concd., chromd. (silica, MeOH/CH2Cl2), evapd., dissolved (TFA/CH2Cl2=1:1) stirred for 1 h, concd. (under N2), triturated (ether), ppt. filtered off, dried (vac.),..;
DOI:10.1021/ja0510360

Reference yield: 59.0%

: 4-methyl-2,2'-bipyridine-4-tyrosine tert-butyl ester

: 862075-55-6
tricarbonyl(diphenylphosphinobenzoic acid)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

: [Re(CO)3((C₆H₅)2PC₆H₄CONHCH(CH₂C₆H₄OH)COOH)(C₁₂H₈N₂)]⁽¹⁺⁾*PF₆^(1-)=[Re(CO)3((C₆H₅)2PC₆H₄CONHCH(C₇H₇O)COOH)(C₁₂H₈N₂)][PF₆]

Guidance literature:: With WSC*HCl; 1-hydroxybenzotriazole; N-methylmorpholine; In dichloromethane; 1:1 mixt. of metal compd. and ligand mixed with WSC*HCl (1.1 equiv.) andHOBt (1.1 equiv.), N-methylmorpholine (4 equiv. added); stirred overnight, evapd., dissolved (CH2Cl2), washed (water), org. layer dried (MgSO4), concd., chromd. (silica, MeOH/CH2Cl2), evapd., dissolved (TFA/CH2Cl2=1:1) stirred for 1 h, concd. (under N2), triturated (ether), ppt. filtered off, dried (vac.),..;
DOI:10.1021/ja0510360