(Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ⁵-phosphanylidene)-oct-5-en-2-one

Base Information

• Chemical Name: (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ⁵-phosphanylidene)-oct-5-en-2-one
• CAS No.: 83200-04-8
• Molecular Formula: C₃₁H₃₅O₂P
• Molecular Weight: 470.591

Synonyms:(Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ⁵-phosphanylidene)-oct-5-en-2-one

Chemical Property of (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ⁵-phosphanylidene)-oct-5-en-2-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ⁵-phosphanylidene)-oct-5-en-2-one

There total 9 articles about (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ⁵-phosphanylidene)-oct-5-en-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8-acetoxy-3-(3-buten-1-yl)-6-methyl-1-(triphenylphosphoranylidene)-(Z)-5-octen-2-one (83200-03-7) → (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ5-phosphanylidene)-oct-5-en-2-one (83200-04-8)

Guidance literature:

With potassium carbonate; In methanol; at 25 ℃; for 0.5h;

DOI:10.1021/jo00146a025

Reference yield:

(Z)-5-chloro-3-methyl-pent-3-en-1-ol (39149-98-9) → (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ5-phosphanylidene)-oct-5-en-2-one (83200-04-8)

Guidance literature:

Multi-step reaction with 5 steps

1: 74 percent / aq.HCl / CH₂Cl₂ / 1.5 h / 25 °C

2: 72 percent / NaBr / various solvent(s) / 3 h / 25 °C

4: 86 percent / glacial acetic acid / 26 h / 90 °C

5: K₂CO₃ / methanol / 0.5 h / 25 °C

With hydrogenchloride; potassium carbonate; acetic acid; sodium bromide; In methanol; dichloromethane;

DOI:10.1021/jo00146a025

Reference yield:

(tert-Butoxycarbonylmethylene)triphenylphosphorane (86302-43-4,35000-38-5) → (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ5-phosphanylidene)-oct-5-en-2-one (83200-04-8)

Guidance literature:

Multi-step reaction with 5 steps

1: benzene / 1.) 5-10 deg C, 5 min, 2.) 25 deg C, 30 min

2: NaOMe / methanol / 1 h / 25 °C

4: 86 percent / glacial acetic acid / 26 h / 90 °C

5: K₂CO₃ / methanol / 0.5 h / 25 °C

With sodium methylate; potassium carbonate; acetic acid; In methanol; benzene;

DOI:10.1021/jo00146a025

upstream raw materials:

8-acetoxy-3-(3-buten-1-yl)-6-methyl-1-(triphenylphosphoranylidene)-(Z)-5-octen-2-one

(Z)-5-chloro-3-methyl-pent-3-en-1-ol

(tert-Butoxycarbonylmethylene)triphenylphosphorane

t-Butyl 5-Chloro-3-oxo-2-(triphenylphosphoranylidene)-pentanoate

Downstream raw materials:

(+/-)-(Z)-3-methyl-6-isopropenyl-3,9-decadien-1-ol acetate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 83200-04-8 (Z)-3-But-3-enyl-8-hydroxy-6-methyl-1-(triphenyl-λ⁵-phosphanylidene)-oct-5-en-2-one

Send

Send

Metric Ton KG G Pound L ML

Send

Send