H₂BCl * tetrahydrofuran

Base Information

• Chemical Name: H₂BCl * tetrahydrofuran
• CAS No.: 55606-72-9
• Molecular Formula: C₄H₁₀BClO
• Molecular Weight: 120.387
• Mol file: 55606-72-9.mol

Synonyms:H₂BCl * tetrahydrofuran

Chemical Property of H₂BCl * tetrahydrofuran

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of H₂BCl * tetrahydrofuran

There total 4 articles about H₂BCl * tetrahydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetramethylammonium octahydrotriborate → H2BCl * tetrahydrofuran (55606-72-9) + dibutoxyborane (22694-36-6) + boric acid tributyl ester (688-74-4)

Guidance literature:

With HgCl₂ or Hg₂Cl₂; In tetrahydrofuran; byproducts: H2; vacuum line; condensation of THF onto mixt. of 2 equiv. of borate and 1 equiv. of HgCl2 or Hg2Cl2, warming to room temp. (overnight, stirring), freezing, pumping off of H2, filtration; not isolated, detd. by (11)B-NMR spectroscopy;

DOI:10.1016/S0020-1693(00)93871-4

Reference yield:

[(PPh3)2Hg2Cl4] + tetramethylammonium octahydrotriborate → H2BCl * tetrahydrofuran (55606-72-9) + dibutoxyborane (22694-36-6) + (C4H8O)B3H7 + (C6H5)3PB3H7 + boric acid tributyl ester (688-74-4)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; 4 equiv. of borate; not isolated, detd. by (11)B-NMR spectroscopy;

DOI:10.1016/S0020-1693(00)93871-4

Reference yield:

2(CH3)4N(1+)*Hg3Cl6(2-)=((CH3)4N)2[Hg3Cl6] + tetramethylammonium octahydrotriborate → H2BCl * tetrahydrofuran (55606-72-9) + (CH3)3NB3H7 + (C4H8O)B3H7 + boric acid tributyl ester (688-74-4)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; stirring of borate with 2 equiv. of Hg-complex; concn.; (11)B-NMR spectroscopy;

DOI:10.1016/S0020-1693(00)93871-4

upstream raw materials:

tetrahydrofuran

borane-THF

C₆H₄(NP(S)(N(C₂H₅)2)2)2PCl

Downstream raw materials:

borane-THF

H₂ClBNH₃

Refernces

• 1、 Young, Susan M.,Carperos, Vasili,Norman, Arlan D.. "Synthesis and Coordination of a Cleft-Stabilized Triphosphazane Hydride: C6H4N2[P(S)(NEt2)2] 2PH". . p. 2000 - 2005. Retrieved 2008/10/09.