methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Base Information

Chemical Name:methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside
CAS No.:158610-43-6
Molecular Formula:C₃₁H₄₂O₁₀
Molecular Weight:574.668
Hs Code.:

Synonyms:methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

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Technology Process of methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

There total 6 articles about methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 69558-12-9
methyl 4-O-benzyl-2-O-methyl-α-L-rhamnopyranoside

: 1,3-di-O-acetyl-4-O-benzyl-2-O-methyl-L-rhamnopyranose

: 158610-43-6
methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Guidance literature:: With 4 A molecular sieve; boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 2h;

Reference yield:

: 89821-78-3
allyl 4-O-benzyl-α-L-rhamnopyranoside

: 158610-43-6
methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) Bu₂SnO / 1.) benzene, reflux, 3 h, 2.) DMF, 90 deg C, 3 h

2: 86 percent / NaH / tetrahydrofuran / 1.) 2 h, 2.) 3 h

3: (Ph₃P)3RhCl / aq. ethanol; benzene / 18 h

4: HgCl₂, HgO, H₂O / acetone / 2 h

5: pyridine, DMAP / CHCl₃ / 12 h

6: 60 percent / 4 Angstroem molecular sieves, BF₃*Et₂O / CH₂Cl₂ / 2 h / 0 °C

With pyridine; dmap; 4 A molecular sieve; boron trifluoride diethyl etherate; water; sodium hydride; di(n-butyl)tin oxide; mercury dichloride; mercury(II) oxide; Wilkinson's catalyst; In tetrahydrofuran; ethanol; dichloromethane; chloroform; acetone; benzene;

Reference yield:

: 158610-40-3
allyl 3-O-allyl-4-O-benzyl-α-L-rhamnopyranoside

: 158610-43-6
methyl 4-O-benzyl-2-O-methyl-3-O-(3-O-acetyl-4-O-benzyl-2-O-methyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 86 percent / NaH / tetrahydrofuran / 1.) 2 h, 2.) 3 h

2: (Ph₃P)3RhCl / aq. ethanol; benzene / 18 h

3: HgCl₂, HgO, H₂O / acetone / 2 h

4: pyridine, DMAP / CHCl₃ / 12 h

5: 60 percent / 4 Angstroem molecular sieves, BF₃*Et₂O / CH₂Cl₂ / 2 h / 0 °C

With pyridine; dmap; 4 A molecular sieve; boron trifluoride diethyl etherate; water; sodium hydride; mercury dichloride; mercury(II) oxide; Wilkinson's catalyst; In tetrahydrofuran; ethanol; dichloromethane; chloroform; acetone; benzene;