Re(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)={Re(CO)3(P(C₆H₁₁)3)2}{B(C₆H₃(CF₃)2)4}

Base Information

• Chemical Name: Re(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)={Re(CO)3(P(C₆H₁₁)3)2}{B(C₆H₃(CF₃)2)4}
• CAS No.: 189058-27-3
• Molecular Formula: C₃₂H₁₂BF₂₄*C₃₉H₆₆O₃P₂Re
• Molecular Weight: 1694.33
• Mol file: 189058-27-3.mol

Synonyms:Re(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)={Re(CO)3(P(C₆H₁₁)3)2}{B(C₆H₃(CF₃)2)4}

Chemical Property of Re(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)={Re(CO)3(P(C₆H₁₁)3)2}{B(C₆H₃(CF₃)2)4}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Re(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)={Re(CO)3(P(C₆H₁₁)3)2}{B(C₆H₃(CF₃)2)4}

There total 1 articles about Re(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)={Re(CO)3(P(C₆H₁₁)3)2}{B(C₆H₃(CF₃)2)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[trans-mer-Re(H2)(PCy3)2(CO)3][B(3,5-(CF3)2C6H3)4] (155963-05-6) → Re(CO)3(P(C6H11)3)2(1+)*B(C6H3(CF3)2)4(1-)={Re(CO)3(P(C6H11)3)2}{B(C6H3(CF3)2)4} (189058-27-3)

Guidance literature:

In dichloromethane-d2; byproducts: H2; dissolution in CD2Cl2 in vac. at 297 K;

DOI:10.1021/ja00089a066

Reference yield:

Re(CO)3(P(C6H11)3)2(1+)*B(C6H3(CF3)2)4(1-)={Re(CO)3(P(C6H11)3)2}{B(C6H3(CF3)2)4} (189058-27-3) → Re(N2)(CO)3(P(C6H11)3)2(1+) (155977-47-2)

Guidance literature:

With N₂; In not given; under 0.8 atm N2; detected by NMR;

DOI:10.1021/ja00089a066

Reference yield:

Re(CO)3(P(C6H11)3)2(1+)*B(C6H3(CF3)2)4(1-)={Re(CO)3(P(C6H11)3)2}{B(C6H3(CF3)2)4} (189058-27-3) → Re(H2O)(CO)3(P(C6H11)3)2(1+) (155977-51-8)

Guidance literature:

With H₂O; In not given; detected by NMR;

DOI:10.1021/ja00089a066

upstream raw materials:

[trans-mer-Re(H₂)(PCy₃)2(CO)3][B(3,5-(CF₃)2C₆H₃)4]

Downstream raw materials:

Re(N₂)(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾

Re(H₂O)(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾