dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate

Base Information

• Chemical Name: dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate
• CAS No.: 1610016-14-2
• Molecular Formula: C₁₈H₂₆O₄S₂
• Molecular Weight: 370.534
• Mol file: 1610016-14-2.mol

Synonyms:dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate

Chemical Property of dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate

There total 1 articles about dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1,4-bis(mercaptomethyl)-2,5-dimethylbenzene (6176-91-6) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate (1610016-14-2)

Guidance literature:

With edetate disodium; In tetrahydrofuran; methanol; at -78 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/ejoc.201301636

Reference yield: 100.0%

dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate (1610016-14-2) → dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenesulfinyl)]-dipropanoate

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃;

DOI:10.1002/ejoc.201301636

Reference yield:

dimethyl 3,3-[(2,5-dimethyl-1,4-phenylene)bis(methylenethio)]dipropanoate (1610016-14-2) → C14H20O4S2

Guidance literature:

Multi-step reaction with 2 steps

1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / -78 °C

2: 1,2-dichloro-ethane / Reflux

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 1,2-dichloro-ethane;

DOI:10.1002/ejoc.201301636

upstream raw materials:

1,4-bis(mercaptomethyl)-2,5-dimethylbenzene

acrylic acid methyl ester