(phenylphosphine)tetracarbonyl iron

Base Information

• Chemical Name: (phenylphosphine)tetracarbonyl iron
• CAS No.: 38967-73-6
• Molecular Formula: C₁₀H₇FeO₄P
• Molecular Weight: 277.984
• Mol file: 38967-73-6.mol

Synonyms:(phenylphosphine)tetracarbonyl iron

Chemical Property of (phenylphosphine)tetracarbonyl iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (phenylphosphine)tetracarbonyl iron

There total 2 articles about (phenylphosphine)tetracarbonyl iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + phenylphosphane (638-21-1) → (phenylphosphine)tetracarbonyl iron (38967-73-6)

Guidance literature:

In octane; stirred at 80-90°C under inert conditions for 50 h; evapd. (0.1 torr/20°C);

DOI:10.1016/S0022-328X(00)89154-8

Reference yield:

diiron nonacarbonyl (15321-51-4) + phenylphosphane (638-21-1) → (phenylphosphine)tetracarbonyl iron (38967-73-6)

Guidance literature:

In toluene; stirring PhPH2 in toluene with Fe2(CO)9 at room temp. in dark; filtration, not sepd.;

Reference yield: 75.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + (phenylphosphine)tetracarbonyl iron (38967-73-6) → μ3-(phenylphosphinidene)-cyclo-tris(tricarbonylcobalt) + 1,1,1,2,2,2,3,3,3-nonacarbonyl-μ3-phenylphosphinediyl-triangulo-dicobaltiron

Guidance literature:

In toluene; Irradiation (UV/VIS); 24 h; distn., chromy., evapn., crystn. from benzene and n-hexane at -25°C; elem. anal.;

upstream raw materials:

iron pentacarbonyl

phenylphosphane

diiron nonacarbonyl

Downstream raw materials:

tetracarbonyl(1,1,2,3,3-pentaphenyltriphosphine-P⁽²⁾)iron⁽⁰⁾

dimanganese decacarbonyl