(S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol

Base Information

Chemical Name:(S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol
CAS No.:144271-02-3
Molecular Formula:C₁₈H₂₆O₄S
Molecular Weight:339.46
Hs Code.:

Synonyms:(S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol

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Chemical Property of (S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol

Chemical Property:

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Technology Process of (S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol

There total 12 articles about (S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₄H₄₃⁽²⁾HO₄SSi

: 144271-02-3
(S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; Yield given;

Reference yield:

: 5390-04-5
pent-1-yn-5-ol

: 144271-02-3
(S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol

Guidance literature:: Multi-step reaction with 12 steps

1: 98 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 2 h / Ambient temperature

2: 1.) n-butyl lithium / 1.) THF, hexane, -70 deg C, 3 h, 2.) THF, hexane, 0 deg C, 10 h

3: 1.) CuI / 1.) THF, -30 deg C, 2.) THF, -78 deg C, 1 h

4: 89 percent / LiAl⁽²⁾H₄ / diethyl ether / 4 h / -10 °C

5: 71 percent / MnO₂ / CH₂Cl₂ / 21 h / Ambient temperature

6: 87 percent / 9-borabicyclo<3.3.1>nonane, 1-(R)-α-pinene / tetrahydrofuran / 9 h / Ambient temperature

7: imidazole / CH₂Cl₂; dimethylformamide / 3 h / Ambient temperature

8: 0.1 N HCl / tetrahydrofuran / 9 h / Ambient temperature

9: 1.) oxalyl chloride, DMSO, 2.) triethylamine / 1.) CH₂Cl₂, -75 deg C, 20 min., 2.) CH₂Cl₂, -75 deg C, 1 h

10: 1.) nBuLi, 3.) nBuLi

11: 4-dimethylaminopyridine (DMAP) / CH₂Cl₂

12: tetra-n-butylammonium fluoride trihydrate / tetrahydrofuran / 0 °C

With 1H-imidazole; hydrogenchloride; dmap; manganese(IV) oxide; copper(l) iodide; 9-borabicyclo[3.3.1]nonane dimer; n-butyllithium; lithium aluminium deuteride; oxalyl dichloride; (+)-α-pinene; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 173439-57-1
5-(2-Ethoxy-ethoxy)-pent-1-yne

: 144271-02-3
(S,Z,E)-<1-2H>-3,7-dimethyl-9-<((4-methylphenyl)sulfonyl)oxy>-2,6-nonadien-1-ol

Guidance literature:: Multi-step reaction with 11 steps

1: 1.) n-butyl lithium / 1.) THF, hexane, -70 deg C, 3 h, 2.) THF, hexane, 0 deg C, 10 h

2: 1.) CuI / 1.) THF, -30 deg C, 2.) THF, -78 deg C, 1 h

3: 89 percent / LiAl⁽²⁾H₄ / diethyl ether / 4 h / -10 °C

4: 71 percent / MnO₂ / CH₂Cl₂ / 21 h / Ambient temperature

5: 87 percent / 9-borabicyclo<3.3.1>nonane, 1-(R)-α-pinene / tetrahydrofuran / 9 h / Ambient temperature

6: imidazole / CH₂Cl₂; dimethylformamide / 3 h / Ambient temperature

7: 0.1 N HCl / tetrahydrofuran / 9 h / Ambient temperature

8: 1.) oxalyl chloride, DMSO, 2.) triethylamine / 1.) CH₂Cl₂, -75 deg C, 20 min., 2.) CH₂Cl₂, -75 deg C, 1 h

9: 1.) nBuLi, 3.) nBuLi

10: 4-dimethylaminopyridine (DMAP) / CH₂Cl₂

11: tetra-n-butylammonium fluoride trihydrate / tetrahydrofuran / 0 °C

With 1H-imidazole; hydrogenchloride; dmap; manganese(IV) oxide; copper(l) iodide; 9-borabicyclo[3.3.1]nonane dimer; n-butyllithium; lithium aluminium deuteride; oxalyl dichloride; (+)-α-pinene; tetrabutyl ammonium fluoride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;