[nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]

Base Information

Chemical Name:[nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]
CAS No.:74170-96-0
Molecular Formula:C₃₈H₄₁B₈P₂Rh
Molecular Weight:749.085
Hs Code.:

[nido-9,9-(PPh<sub>3</sub>)2-9,7,8-RhC<sub>2</sub>B<sub>8</sub>H<sub>11</sub>]

Synonyms:[nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]

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Chemical Property of [nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]

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Technology Process of [nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]

There total 2 articles about [nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: bis(ethylene)rhodium(I) chloride dimer

: Na⁽¹⁺⁾*C₂B₈H₁₁^(1-) = NaC₂B₈H₁₁

: 74170-96-0
[nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]

Guidance literature:: With triphenylphosphine; In diethyl ether; (Ar or N2), PPh3 added to a stirred susp. of Rh-complex, after 10 min soln. of NaC2B8H11 in Et2O added, stirred overnight; filtered, washed with Et2O, extracted with CH2Cl2, EtOH layered on top of filtrate, allowed to stand at room temp. dor 2 days, cooled to 0°C for several hours, filtered in air, washed with EtOH and petroleum ether, vac. dried; elem. anal.;
DOI:10.1021/ja00529a026

Reference yield: 42.0%

: 14694-95-2
Wilkinson's catalyst

: 86457-95-6,41655-26-9
dicarba-nido-decaborane⁽¹²⁾

: 74170-96-0
[nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]

Guidance literature:: In ethanol; (Ar or N2), Rh-complex and C2B8H12 reacted in refluxing EtOH for 2. 5 h, cooled to room temp.; filtered, washed with ethanol, recrystd. from CH2Cl2-MeOH;
DOI:10.1021/ja00529a026

Reference yield: 73.0%

: 74170-96-0
[nido-9,9-(PPh₃)2-9,7,8-RhC₂B₈H₁₁]

: 696-26-4
dimethylphenylarsine

: 74171-01-0
[nido-9,9,9-(As(CH₃)2Ph)3-9,7,8-RhC₂B₈H₁₁]

Guidance literature:: In toluene; (N2 or Ar), AsMe2Ph added using a gas-tight syring to a soln. of B-complex in toluene, after 10 min petroleum ether layered above the soln., mixture allowed to stand overnight at room temp., cooled to -15°C for several hours; filtered in air, washed with petroleum ether, vac. dried; IR, 11B and 1H-NMR;
DOI:10.1021/ja00529a026