(1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate

Base Information

Chemical Name:(1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate
CAS No.:1169983-31-6
Molecular Formula:C₁₆H₁₈N₂O₄
Molecular Weight:302.33
Hs Code.:

Synonyms:(1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate

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Technology Process of (1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate

There total 3 articles about (1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 930-88-1
N-methylmaleimide

: 355425-48-8
N-(2-methylbenzylidene)-glycine methyl ester

: 1140972-14-0
methyl (1S,3R,3aS,6aR)-5-methyl-4,6-dioxo-3-o-tolyloctahydropyrrolo[3,4-c]pyrrole-1-carboxylate

: 1169983-31-6
(1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate

Guidance literature:: With (Sa)-Binap-AuTFA; In toluene; at 20 ℃; for 48h; optical yield given as %ee; enantioselective reaction;
DOI:10.1016/j.tetasy.2010.06.011

Reference yield:

: 930-88-1
N-methylmaleimide

: 355425-48-8
N-(2-methylbenzylidene)-glycine methyl ester

: 1169983-31-6
(1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate

Guidance literature:: With (S)-TF-Biphamphos; silver(I) acetate; In dichloromethane; at 20 ℃; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1039/b902556a

Reference yield:

: 930-88-1
N-methylmaleimide

: C₁₁H₁₂N₂O₂

: 1140972-14-0
methyl (1S,3R,3aS,6aR)-5-methyl-4,6-dioxo-3-o-tolyloctahydropyrrolo[3,4-c]pyrrole-1-carboxylate

: 1169983-31-6
(1R,3S,3aR,6aS)-methyl octahydro-5-methyl-4,6-dioxo-3-o-tolylpyrrolo[3,4-c]pyrrole-1-carboxylate

Guidance literature:: With silver perchlorate; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine); triethylamine; In toluene; at 20 ℃; optical yield given as %ee; diastereoselective reaction; Darkness;
DOI:10.1016/j.tetasy.2008.12.021