Technology Process of 3,4-dimethoxy-2,5-bis(benzyloxy)benzyl tert-butyldimethylsilyl ether
There total 4 articles about 3,4-dimethoxy-2,5-bis(benzyloxy)benzyl tert-butyldimethylsilyl ether which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 98 percent / diisopropylethylamine / dimethylformamide / 0.5 h
2: 1.) sodium borohydride, 2.) potassium carbonate / 1.) EtOH, 5 min, 2.) reflux, 24 h
With
sodium tetrahydroborate; potassium carbonate; N-ethyl-N,N-diisopropylamine;
In
N,N-dimethyl-formamide;
DOI:10.1021/jo00278a023
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 80 percent / sodium acetate, potassium nitrosodisulfonate (Fremy's salt) / methanol; H2O
2: 98 percent / diisopropylethylamine / dimethylformamide / 0.5 h
3: 1.) sodium borohydride, 2.) potassium carbonate / 1.) EtOH, 5 min, 2.) reflux, 24 h
With
sodium tetrahydroborate; potassium nitrososulfonate; sodium acetate; potassium carbonate; N-ethyl-N,N-diisopropylamine;
In
methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00278a023
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 75 percent / tetrabutylammonium fluoride / tetrahydrofuran / 0.17 h
2: 80 percent / sodium acetate, potassium nitrosodisulfonate (Fremy's salt) / methanol; H2O
3: 98 percent / diisopropylethylamine / dimethylformamide / 0.5 h
4: 1.) sodium borohydride, 2.) potassium carbonate / 1.) EtOH, 5 min, 2.) reflux, 24 h
With
sodium tetrahydroborate; potassium nitrososulfonate; tetrabutyl ammonium fluoride; sodium acetate; potassium carbonate; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00278a023
