1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

Base Information

Chemical Name:1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal
CAS No.:216770-46-6
Molecular Formula:C₂₄H₃₇O₁₀PS₂
Molecular Weight:580.658
Hs Code.:

Synonyms:1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

Suppliers and Price of 1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

There total 2 articles about 1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 14273-92-8
methyl 5-hydroxypentanoate

: 55894-94-5
Bis<1,2-dimethylethenylene>pyrophosphate

: 216770-35-3
1-O-benzyl-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

: 216770-46-6
1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

Guidance literature:: methyl 5-hydroxypentanoate; Bis<1,2-dimethylethenylene>pyrophosphate; With triethylamine; In dichloromethane; at 20 ℃; for 1h;

1-O-benzyl-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal; With triethylamine; In dichloromethane; at 20 ℃; for 6h;
DOI:10.1080/07328309808001895

Reference yield:

: 130114-53-3,130114-54-4
(3S,4S)-2-Benzyloxymethyl-tetrahydro-furan-2,3,4-triol

: 216770-46-6
1-O-benzyl-5-O-[1-(4-methoxycarbonylbutyl)-2-(3-oxobutyl)]-phosphono-L-erythro-pent-2-ulose ethane-1,2-diyl dithioacetal

Guidance literature:: Multi-step reaction with 2 steps

1.1: 75 percent / HCl / H₂O / 0.5 h / 0 °C

2.1: triethylamine / CH₂Cl₂ / 1 h / 20 °C

2.2: 58 percent / triethylamine / CH₂Cl₂ / 6 h / 20 °C

With hydrogenchloride; triethylamine; In dichloromethane; water; 1.1: thioketalisation / 2.1: Esterification / 2.2: Substitution;
DOI:10.1080/07328309808001895