Technology Process of 1,4-dihexyloxy-2,3-dipropargylbenzene
There total 5 articles about 1,4-dihexyloxy-2,3-dipropargylbenzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
1,4-dihexyloxy-2,3-bis(3-trimethylsilyl-2-propynyl)benzene;
With
silver nitrate;
In
dichloromethane; water; acetone;
at 20 ℃;
for 0.75h;
Darkness;
Inert atmosphere;
With
hydrogenchloride;
In
dichloromethane; water; acetone;
for 1h;
Inert atmosphere;
DOI:10.1021/ma201749n
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: potassium carbonate / acetonitrile / 25 h / Reflux; Inert atmosphere
2.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 0.5 h / Reflux; Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran; hexane / 0.83 h / Inert atmosphere
3.2: -78 - 50 °C / Inert atmosphere
4.1: silver nitrate / dichloromethane; water; acetone / 0.75 h / 20 °C / Darkness; Inert atmosphere
4.2: 1 h / Inert atmosphere
With
N-Bromosuccinimide; n-butyllithium; 2,2'-azobis(isobutyronitrile); potassium carbonate; silver nitrate;
In
tetrahydrofuran; tetrachloromethane; hexane; dichloromethane; water; acetone; acetonitrile;
DOI:10.1021/ma201749n
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.83 h / Inert atmosphere
1.2: -78 - 50 °C / Inert atmosphere
2.1: silver nitrate / dichloromethane; water; acetone / 0.75 h / 20 °C / Darkness; Inert atmosphere
2.2: 1 h / Inert atmosphere
With
n-butyllithium; silver nitrate;
In
tetrahydrofuran; hexane; dichloromethane; water; acetone;
DOI:10.1021/ma201749n
