2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol

Base Information

Chemical Name:2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol
CAS No.:1449682-56-7
Molecular Formula:C₃₀H₃₁IO₄
Molecular Weight:582.478
Hs Code.:

Synonyms:2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol

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Chemical Property of 2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol

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Technology Process of 2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol

There total 2 articles about 2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1101199-96-5
1-O-acetyl-2,6-anhydro-3,4,5-tri-O-benzyl-7,8,9-trideoxy-D-glycero-L-gulo-non-7-ynitol

: 1449682-56-7
2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol

Guidance literature:: 1-O-acetyl-2,6-anhydro-3,4,5-tri-O-benzyl-7,8,9-trideoxy-D-glycero-L-gulo-non-7-ynitol; With potassium hydroxide; In methanol; at 20 ℃; for 2h;

With 1H-imidazole; iodine; triphenylphosphine; In benzene; for 0.75h; Reflux;
DOI:10.1002/chem.201301230

Reference yield:

: 1101199-95-4
2,6-anhydro-1,3,4,5-tetra-O-benzyl-7,8,9-trideoxy-D-glycero-L-gulo-non-7-ynitol

: 1449682-56-7
2,6-anhydro-3,4,5-tri-O-benzyl-1,7,8,9-tetradeoxy-1-iodo-D-glycero-L-gulo-non-7-ynitol

Guidance literature:: Multi-step reaction with 2 steps

1.1: zinc(II) chloride; acetic acid / 0.75 h / 0 °C / Inert atmosphere

2.1: potassium hydroxide / methanol / 2 h / 20 °C

2.2: 0.75 h / Reflux

With acetic acid; potassium hydroxide; zinc(II) chloride; In methanol;
DOI:10.1002/chem.201301230