trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

Base Information

Chemical Name:trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside
CAS No.:367518-26-1
Molecular Formula:C₂₄H₂₅Cl₃N₄O₆
Molecular Weight:571.845
Hs Code.:

Synonyms:trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

Suppliers and Price of trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

There total 7 articles about trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 545-06-2
trichloroacetonitrile

: 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α,β-D-glucopyranose

: 367518-26-1
trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

Guidance literature:: With potassium carbonate; In dichloromethane;
DOI:10.1002/1521-3765(20001002)6:19<3608::AID-CHEM3608>3.0.CO;2-Q

Reference yield:

: 202462-37-1
phenyl 2-azido-2-deoxy-1-thio-α/β-D-glucopyranoside

: 367518-26-1
trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: TsOH

2: NaH / dimethylformamide

3: NaCNBH₃; HCl / diethyl ether

4: NEt₃; DMAP / CH₂Cl₂

5: 93 percent / NBS; H₂O / acetone

6: 89 percent / K₂CO₃ / CH₂Cl₂

With hydrogenchloride; dmap; N-Bromosuccinimide; water; sodium hydride; sodium cyanoborohydride; potassium carbonate; toluene-4-sulfonic acid; triethylamine; In diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1002/1521-3765(20001002)6:19<3608::AID-CHEM3608>3.0.CO;2-Q

Reference yield:

: 183875-22-1
phenyl 2-azido-2-deoxy-3,4,6-tri-O-acetyl-1-thio-α/β-D-glucopyranoside

: 367518-26-1
trichloroacetoimidoyl 4-O-acetyl-2-azido-3,6-di-O-benzyl-2-deoxy-α/β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1: NaOMe / methanol

2: TsOH

3: NaH / dimethylformamide

4: NaCNBH₃; HCl / diethyl ether

5: NEt₃; DMAP / CH₂Cl₂

6: 93 percent / NBS; H₂O / acetone

7: 89 percent / K₂CO₃ / CH₂Cl₂

With hydrogenchloride; dmap; N-Bromosuccinimide; water; sodium methylate; sodium hydride; sodium cyanoborohydride; potassium carbonate; toluene-4-sulfonic acid; triethylamine; In methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1002/1521-3765(20001002)6:19<3608::AID-CHEM3608>3.0.CO;2-Q