1-chloro-2-(cyclopropylidenemethyl)benzene

Base Information

• Chemical Name: 1-chloro-2-(cyclopropylidenemethyl)benzene
• CAS No.: 7555-68-2
• Molecular Formula: C₁₀H₉Cl
• Molecular Weight: 164.634
• Mol file: 7555-68-2.mol

Synonyms:1-chloro-2-(cyclopropylidenemethyl)benzene

Chemical Property of 1-chloro-2-(cyclopropylidenemethyl)benzene

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-chloro-2-(cyclopropylidenemethyl)benzene

There total 2 articles about 1-chloro-2-(cyclopropylidenemethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-bromopropyltriphenylphosphonium bromide (3607-17-8) + 2-chloro-benzaldehyde (89-98-5) → 1-chloro-2-(cyclopropylidenemethyl)benzene (7555-68-2)

Guidance literature:

3-bromopropyltriphenylphosphonium bromide; With potassium tert-butylate; In tetrahydrofuran; at 70 ℃; for 1h; Inert atmosphere; Schlenk technique;

2-chloro-benzaldehyde; In tetrahydrofuran; for 3h; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1039/c9cc08077e

Reference yield:

→ 1-chloro-2-(cyclopropylidenemethyl)benzene (7555-68-2)

Guidance literature:

2-Chlor-benzaldehyd 1.Triphenylphosphincyclopropylen 2.HBr 3.Kalium-tert.-butylat;

DOI:10.1016/S0040-4039(01)82833-1

Reference yield: 93.0%

3-phenylbenzo[d]isothiazole-1,1-dioxide (53440-57-6) + 1-chloro-2-(cyclopropylidenemethyl)benzene (7555-68-2) → (E)-2'-(2-chlorophenyl)-3'-ethylidene-2',3'-dihydro-2H-spiro[benzo[d]isothiazole-3,1'-indene] 1,1-dioxide

Guidance literature:

With [Ru(C₅Me₅)(MeCN)₃](SbF₆)₂; copper diacetate; In tert-Amyl alcohol; at 100 ℃; for 18h; regioselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1039/c9cc09621c

upstream raw materials:

3-bromopropyltriphenylphosphonium bromide

2-chloro-benzaldehyde

Downstream raw materials:

C₁₆H₁₂ClN₃O₂

N-(2-(4-(2-chlorophenyl)-5-oxa-6-azaspiro[2.4]hept-6-en-7-yl)phenyl)formamide

2-(2-chlorophenyl)cyclobutanone