(1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol

Base Information

Chemical Name:(1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol
CAS No.:166757-84-2
Molecular Formula:C₁₄H₁₈O₂
Molecular Weight:218.296
Hs Code.:

Synonyms:(1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol

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Chemical Property of (1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol

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Technology Process of (1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol

There total 9 articles about (1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: C₂₁H₂₄O₂

: 166757-84-2
(1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/ja00137a026

Reference yield: 99.0%

: 194656-80-9
(1R,5R)-1-Methyl-3-phenyl-2,4-dioxa-bicyclo[3.3.1]non-6-ene

: 166757-84-2
(1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol

Guidance literature:: With diisobutylaluminium hydride; In hexane; dichloromethane; for 5h; Ambient temperature;
DOI:10.1002/ijch.199700004

Reference yield:

: 101917-46-8
(3aS,4R,6R,7aR)-6-Hydroxymethyl-2,2-dimethyl-hexahydro-benzo[1,3]dioxole-4,6-diol

: 166757-84-2
(1R,5R)-5-Benzyloxy-5-methyl-cyclohex-2-enol

Guidance literature:: Multi-step reaction with 7 steps

1: 71 percent / DMAP / pyridine / 49 h / Ambient temperature

2: 99 percent / DBU / benzene / 0.5 h / Ambient temperature

3: 100 percent / LiAlH₄ / tetrahydrofuran / 1 h / Ambient temperature

4: 98 percent / Et₃N / CH₂Cl₂ / 0.67 h / 0 °C

5: 85 percent / Na, NH₃ / tetrahydrofuran / 1.25 h / -78 °C

6: 72 percent / 4A molecular sieves, p-TSA / CH₂Cl₂ / 24 h / 20 °C

7: 99 percent / DIBAL / CH₂Cl₂; hexane / 5 h / Ambient temperature

With dmap; lithium aluminium tetrahydride; 4 A molecular sieve; ammonia; sodium; diisobutylaluminium hydride; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; pyridine; hexane; dichloromethane; benzene;
DOI:10.1002/ijch.199700004