2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate

Base Information

Chemical Name:2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate
CAS No.:1417719-92-6
Molecular Formula:C₁₅H₂₅N₃O₈Si
Molecular Weight:403.464
Hs Code.:

Synonyms:2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate

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Chemical Property of 2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate

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Technology Process of 2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate

There total 3 articles about 2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 485809-82-3
3-azido-2,4,6-tri-O-acetyl-3-deoxy-α-D-glucopyranosyl trichloroacetimidate

: 1417719-90-4
C₃₄H₄₀N₆O₁₃

: C₃₄H₄₀N₆O₁₃

: 1417719-92-6
2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -80 ℃; for 2h;
DOI:10.1016/j.tet.2012.10.058

Reference yield:

: 185114-94-7,155417-78-0
1,2,4,6-Tetra-O-acetyl-3-azido-3-deoxy-α/β-gluco-hexopyranose

: 1417719-90-4
C₃₄H₄₀N₆O₁₃

: C₃₄H₄₀N₆O₁₃

: 1417719-92-6
2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate

Guidance literature:: Multi-step reaction with 3 steps

1: ammonium acetate / N,N-dimethyl-formamide / 18 h

2: caesium carbonate / dichloromethane / 4 h

3: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 2 h / -80 °C

With ammonium acetate; trimethylsilyl trifluoromethanesulfonate; caesium carbonate; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2012.10.058

Reference yield:

: 2,4,6-tri-O-acetyl 3-azido-3-deoxy-a-D-glucopyranose

: 1417719-90-4
C₃₄H₄₀N₆O₁₃

: C₃₄H₄₀N₆O₁₃

: 1417719-92-6
2,4,6-tri-O-acetyl-3-azido-3-deoxy-a-D-glucopyranosyl trimethylsilyl triflate

Guidance literature:: Multi-step reaction with 2 steps

1: caesium carbonate / dichloromethane / 4 h

2: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 2 h / -80 °C

With trimethylsilyl trifluoromethanesulfonate; caesium carbonate; In dichloromethane;
DOI:10.1016/j.tet.2012.10.058