(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*Ir(CO)2(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir(CO)2(S₂C₂(CN)2)]

Base Information

• Chemical Name: (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*Ir(CO)2(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir(CO)2(S₂C₂(CN)2)]
• CAS No.: 84623-80-3
• Molecular Formula: C₆IrN₂O₂S₂*C₃₆H₃₀NP₂
• Molecular Weight: 927.019

Synonyms:(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*Ir(CO)2(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir(CO)2(S₂C₂(CN)2)]

Chemical Property of (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*Ir(CO)2(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir(CO)2(S₂C₂(CN)2)]

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Technology Process of (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*Ir(CO)2(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir(CO)2(S₂C₂(CN)2)]

There total 1 articles about (C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*Ir(CO)2(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir(CO)2(S₂C₂(CN)2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tetrabutylammonium bis(carbonyl) maleonitriledithiolate iridium(I) complex + bis(triphenylphosphine)iminium chloride (21050-13-5) → (C6H5)3PNP(C6H5)3(1+)*Ir(CO)2(S2C2(CN)2)(1-) = (C6H5)3PNP(C6H5)3[Ir(CO)2(S2C2(CN)2)] (84623-80-3)

Guidance literature:

In acetone; water was added; filtered; washed with water, ethanol and ether;

DOI:10.1021/ja00345a019

Reference yield: 93.0%

(C6H5)3PNP(C6H5)3(1+)*Ir(CO)2(S2C2(CN)2)(1-) = (C6H5)3PNP(C6H5)3[Ir(CO)2(S2C2(CN)2)] (84623-80-3) + bis(triphenylphosphine)iminium cyanide (65300-07-4) → 2(C6H5)6PNP(1+)*Ir(1+)*CO*CN(1-)*S2C2(CN)2(2-) = [(C6H5)3PNP(C6H5)3]2[Ir(CO)(CN)(S2C2(CN)2)] (84642-25-1)

Guidance literature:

In acetonitrile; byproducts: CO; under N2; to a solution of the Ir-complex was added dropwise a solutionof PPN(CN); concentrated under vacuum; 2-propanol was added; concentrated again (vacuum); was set aside at -20°C for 1 h; collected by filtration; washed twice with 2-propanol and twice with ether; elem. anal.;

DOI:10.1021/ja00345a019

Reference yield: 86.0%

(C6H5)3PNP(C6H5)3(1+)*Ir(CO)2(S2C2(CN)2)(1-) = (C6H5)3PNP(C6H5)3[Ir(CO)2(S2C2(CN)2)] (84623-80-3) → (C6H5)3PNP(C6H5)3(1+)*Ir(CO)(P(C6H5)3)(S2C2(CN)2)(1-) = (C6H5)3PNP(C6H5)3[Ir(CO)(P(C6H5)3)(S2C2(CN)2)] (84623-83-6)

Guidance literature:

With triphenylphosphine; In acetone; byproducts: CO; under N2; acetone was added to the Ir-complex and PPh3; stirred for 10 min; concentrated under vacuum; 2-propanol was added; precipitated; collected by filtration; washed with 2-propanol and ether;

DOI:10.1021/ja00345a019

upstream raw materials:

bis(triphenylphosphine)iminium chloride

Downstream raw materials:

(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*Ir(CO)(P(C₆H₅)3)(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir(CO)(P(C₆H₅)3)(S₂C₂(CN)2)]

(C₆H₅)6PNP⁽¹⁺⁾*Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(S₂C₂(CN)2)^(1-) = (C₆H₅)3PNP(C₆H₅)3[Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(S₂C₂(CN)2)]

2(C₆H₅)6PNP⁽¹⁺⁾*Ir⁽¹⁺⁾*CO*CN^(1-)*S₂C₂(CN)2^(2-) = [(C₆H₅)3PNP(C₆H₅)3]2[Ir(CO)(CN)(S₂C₂(CN)2)]

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