C₄₄H₇₂O₁₀Si

Base Information

Chemical Name:C₄₄H₇₂O₁₀Si
CAS No.:944450-37-7
Molecular Formula:C₄₄H₇₂O₁₀Si
Molecular Weight:789.135
Hs Code.:

C<sub>44</sub>H<sub>72</sub>O<sub>10</sub>Si

Synonyms:C₄₄H₇₂O₁₀Si

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Chemical Property of C₄₄H₇₂O₁₀Si

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Technology Process of C₄₄H₇₂O₁₀Si

There total 14 articles about C₄₄H₇₂O₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 944450-14-0
2-[(1S,2R,6R)-2-(methoxymethoxy)-4-methyl-6-(prop-1-en-2-yl)cyclohex-3-enyl]ethanol

: 944450-37-7
C₄₄H₇₂O₁₀Si

Guidance literature:: Multi-step reaction with 7 steps

1.1: 98 percent / sulfur trioxide-pyridine complex; ethyldiisopropylamine; DMSO / CH₂Cl₂ / 0.67 h / -30 - -15 °C

2.1: 78 percent / Zn(OTf)2; (+)-N-methylephedrine; triethylamine / toluene / 15 h / 20 °C

3.1: tributyltin hydride / dichlorobis[tri(o-tolyl)phosphine]palladium / tetrahydrofuran / 0 - 20 °C

3.2: iodine / diethyl ether / 0.25 h / 0 °C

4.1: tributyltin hydride; lithium diisopropylamide; copper cyanide / tetrahydrofuran; diethyl ether; methanol / 0.25 h / -78 - -25 °C

4.2: 1.56 g / copper(I) chloride / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran; 1-methyl-pyrrolidin-2-one / 10 h / 20 °C

5.1: 85 percent / toluene / 28 h / 205 °C

6.1: 92 percent / ethyldiisopropylamine / CH₂Cl₂ / 2 h

7.1: KHMDS / toluene / 0.03 h / -78 °C

7.2: triethylphosphite; oxygen / toluene / 1.25 h / -78 °C

With tri-n-butyl-tin hydride; copper(l) cyanide; sulfur trioxide pyridine complex; potassium hexamethylsilazane; zinc trifluoromethanesulfonate; (+)-N-methylephedrine; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; dichlorobis(tri-O-tolylphosphine)palladium; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene; 1.1: Parikh-Doering oxidation;
DOI:10.1021/jo070165r

Reference yield:

: 944450-15-1
2-[(1S,2R,6R)-2-(methoxymethoxy)-4-methyl-6-(prop-1-en-2-yl)cyclohex-3-enyl]acetaldehyde

: 944450-37-7
C₄₄H₇₂O₁₀Si

Guidance literature:: Multi-step reaction with 6 steps

1.1: 78 percent / Zn(OTf)2; (+)-N-methylephedrine; triethylamine / toluene / 15 h / 20 °C

2.1: tributyltin hydride / dichlorobis[tri(o-tolyl)phosphine]palladium / tetrahydrofuran / 0 - 20 °C

2.2: iodine / diethyl ether / 0.25 h / 0 °C

3.1: tributyltin hydride; lithium diisopropylamide; copper cyanide / tetrahydrofuran; diethyl ether; methanol / 0.25 h / -78 - -25 °C

3.2: 1.56 g / copper(I) chloride / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran; 1-methyl-pyrrolidin-2-one / 10 h / 20 °C

4.1: 85 percent / toluene / 28 h / 205 °C

5.1: 92 percent / ethyldiisopropylamine / CH₂Cl₂ / 2 h

6.1: KHMDS / toluene / 0.03 h / -78 °C

6.2: triethylphosphite; oxygen / toluene / 1.25 h / -78 °C

With tri-n-butyl-tin hydride; copper(l) cyanide; potassium hexamethylsilazane; zinc trifluoromethanesulfonate; (+)-N-methylephedrine; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; dichlorobis(tri-O-tolylphosphine)palladium; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene;
DOI:10.1021/jo070165r

Reference yield:

: 944450-16-2
(R)-6-(triisopropylsilyloxy)-1-[(1S,2R,6R)-2-(methoxymethoxy)-4-methyl-6-(prop-1-en-2-yl)cyclohex-3-enyl]hex-3-yn-2-ol

: 944450-37-7
C₄₄H₇₂O₁₀Si

Guidance literature:: Multi-step reaction with 5 steps

1.1: tributyltin hydride / dichlorobis[tri(o-tolyl)phosphine]palladium / tetrahydrofuran / 0 - 20 °C

1.2: iodine / diethyl ether / 0.25 h / 0 °C

2.1: tributyltin hydride; lithium diisopropylamide; copper cyanide / tetrahydrofuran; diethyl ether; methanol / 0.25 h / -78 - -25 °C

2.2: 1.56 g / copper(I) chloride / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran; 1-methyl-pyrrolidin-2-one / 10 h / 20 °C

3.1: 85 percent / toluene / 28 h / 205 °C

4.1: 92 percent / ethyldiisopropylamine / CH₂Cl₂ / 2 h

5.1: KHMDS / toluene / 0.03 h / -78 °C

5.2: triethylphosphite; oxygen / toluene / 1.25 h / -78 °C

With tri-n-butyl-tin hydride; copper(l) cyanide; potassium hexamethylsilazane; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; dichlorobis(tri-O-tolylphosphine)palladium; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene;
DOI:10.1021/jo070165r