Technology Process of C14H14BrN
There total 4 articles about C14H14BrN which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
4-tolyl iodide;
With
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran;
for 0.166667h;
C19H17BrFNSi;
With
tetrabutyl ammonium fluoride;
In
tetrahydrofuran;
at 90 ℃;
for 24h;
DOI:10.1021/ol400977r
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: bis(1,5-cyclooctadiene)nickel (0); triphenylphosphine / tetrahydrofuran / 1 h / 90 °C / Glovebox; Inert atmosphere; Schlenk technique
2.1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 1,10-Phenanthroline; norborn-2-ene / tetrahydrofuran / 12 h / 90 °C / Glovebox; Inert atmosphere; Schlenk technique
3.1: silver fluoride; N-Bromosuccinimide / 20 °C / Darkness
4.1: tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 0.17 h
4.2: 24 h / 90 °C
With
norborn-2-ene; bis(1,5-cyclooctadiene)nickel (0); N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium(0); 1,10-Phenanthroline; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; silver fluoride; triphenylphosphine;
In
tetrahydrofuran;
DOI:10.1021/ol400977r
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: silver fluoride; N-Bromosuccinimide / 20 °C / Darkness
2.1: tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 0.17 h
2.2: 24 h / 90 °C
With
N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium(0); silver fluoride;
In
tetrahydrofuran;
DOI:10.1021/ol400977r
