9-methoxy-10-diphenylphosphinophenanthrene

Base Information

• Chemical Name: 9-methoxy-10-diphenylphosphinophenanthrene
• CAS No.: 372189-21-4
• Molecular Formula: C₂₇H₂₁O₂P
• Molecular Weight: 408.436
• Mol file: 372189-21-4.mol

Synonyms:9-methoxy-10-diphenylphosphinophenanthrene

Chemical Property of 9-methoxy-10-diphenylphosphinophenanthrene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-methoxy-10-diphenylphosphinophenanthrene

There total 3 articles about 9-methoxy-10-diphenylphosphinophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(10-methoxy-phenanthren-9-yl)-diphenyl-phosphane → 9-methoxy-10-diphenylphosphinophenanthrene (372189-21-4)

Guidance literature:

With dihydrogen peroxide; In acetic acid; at 80 ℃; for 2h;

DOI:10.1016/S0957-4166(01)00310-X

Reference yield:

9-methoxyphenanthrene (5085-74-5) → 9-methoxy-10-diphenylphosphinophenanthrene (372189-21-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: TMEDA; n-BuLi / diethyl ether; hexane / 2 h / 20 °C

1.2: 2 h

2.1: 0.507 g / aq. H₂O₂ / acetic acid / 2 h / 80 °C

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; dihydrogen peroxide; In diethyl ether; hexane; acetic acid;

DOI:10.1016/S0957-4166(01)00310-X

Reference yield:

chloro-diphenylphosphine (1079-66-9,74391-44-9) → 9-methoxy-10-diphenylphosphinophenanthrene (372189-21-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: TMEDA; n-BuLi / diethyl ether; hexane / 2 h / 20 °C

1.2: 2 h

2.1: 0.507 g / aq. H₂O₂ / acetic acid / 2 h / 80 °C

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; dihydrogen peroxide; In diethyl ether; hexane; acetic acid;

DOI:10.1016/S0957-4166(01)00310-X

upstream raw materials:

9-methoxyphenanthrene

chloro-diphenylphosphine

Downstream raw materials:

(R)-1-[10'-(diphenylphosphinyl)-9'-phenanthrenyl]-2-(methoxymethyl)pyrrolidine