<1S-<1α(5S),3α,4β,5α,6α(2E,4R,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

Base Information

Chemical Name:<1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester
CAS No.:144358-25-8
Molecular Formula:C₄₅H₆₈O₁₂
Molecular Weight:801.028
Hs Code.:

<1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

Synonyms:<1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

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Chemical Property of <1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

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Technology Process of <1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

There total 2 articles about <1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 144358-24-7
<1S-<1α(4R*,5R*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-<4-(acetyloxy)-5-methyl-3-methylene-6-phenylhexyl>4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

: 144358-25-8
<1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

Guidance literature:: With ammonium formate; bis-triphenylphosphine-palladium(II) chloride; In 1,4-dioxane; for 22h; Heating;
DOI:10.1021/jm00046a011

Reference yield:

: 138682-84-5,144786-97-0,146075-86-7,148152-80-1,149656-40-6,142561-96-4
zaragozic acid A

: 144358-25-8
<1S-<1α(5S*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-(5-methyl-3-methylene-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester

Guidance literature:: Multi-step reaction with 2 steps

1: 58 percent / toluene / 2.5 h / Heating

2: 91 percent / ammonium formate / (Ph₃P)2PdCl₂ / dioxane / 22 h / Heating

With ammonium formate; bis-triphenylphosphine-palladium(II) chloride; In 1,4-dioxane; toluene;
DOI:10.1021/jm00046a011