bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

Base Information

Chemical Name:bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)
CAS No.:1283056-81-4
Molecular Formula:C₅₇H₇₅N₃O₁₄S
Molecular Weight:1058.3
Hs Code.:

Synonyms:bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

Suppliers and Price of bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

There total 2 articles about bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1283056-80-3
bis-1,11-[methyl-6-azido-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

: 1283056-81-4
bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

Guidance literature:: With 5%-palladium/activated carbon; triethylamine; In methanol; for 72h;
DOI:10.1016/j.crci.2010.03.032

Reference yield:

: 1283056-62-1
methyl 6-azido-2,3-di-O-benzyl-4-O-(5-chloro-3-oxapentyl)-6-deoxy-α-D-glucopyranoside

: 1283056-81-4
bis-1,11-[methyl-6-amino-2,3-di-O-benzyl-6-deoxy-4-yloxy-α-D-glucopyranoside]-(6-tosyl-3,9-dioxa-6-aza-undecane)

Guidance literature:: Multi-step reaction with 2 steps

1: caesium carbonate / N,N-dimethyl-formamide / 72 h / 80 °C

2: 5%-palladium/activated carbon; triethylamine / methanol / 72 h

With 5%-palladium/activated carbon; caesium carbonate; triethylamine; In methanol; N,N-dimethyl-formamide; 1: Richman-Atkins cyclisation;
DOI:10.1016/j.crci.2010.03.032