(3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate

Base Information

Chemical Name:(3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate
CAS No.:1395418-76-4
Molecular Formula:C₃₃H₃₅BrN₂O₄
Molecular Weight:603.556
Hs Code.:

Synonyms:(3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate

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Chemical Property of (3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate

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Technology Process of (3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate

There total 1 articles about (3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 768-03-6,26742-84-7
Phenyl vinyl ketone

: 209168-88-7
tert-butyl (2-(6-bromo-1H-indol-3-yl)ethyl)carbamate

: 1395418-76-4
(3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate

: (3aS,8aS)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate

Guidance literature:: With (S)-(+)-3,3′-bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate; In toluene; at 0 ℃; for 48h; Overall yield = 94 %; enantioselective reaction; Molecular sieve;
DOI:10.1021/ol302043s

Reference yield:

: 1395418-76-4
(3aR,8aR)-tert-butyl 6-bromo-3a,8-bis(3-oxo-3-phenylpropyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1(2H)-carboxylate

: C₂₈H₂₇BrN₂O₂

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 8h; enantioselective reaction; Molecular sieve;
DOI:10.1021/ol302043s