Nickel(2+) diquinolin-8-olate

Base Information

• Chemical Name: Nickel(2+) diquinolin-8-olate
• CAS No.: 14100-15-3
• Molecular Formula: C18H12 N2 Ni O2
• Molecular Weight: 346.995
• European Community (EC) Number: 237-950-2
• DSSTox Substance ID: DTXSID20930971
• Mol file: 14100-15-3.mol

Synonyms:nickel(2+) diquinolin-8-olate;14100-15-3;EINECS 237-950-2;nickel(2+);quinolin-8-olate;DTXSID20930971;Bis(quinolin-8-olato-N1,O8)nickel

Chemical Property of Nickel(2+) diquinolin-8-olate

Chemical Property:

• Vapor Pressure: 0.00508mmHg at 25°C
• Boiling Point: 267°C at 760 mmHg
• Flash Point: 143.1°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 346.025219
• Heavy Atom Count: 23
• Complexity: 138

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C(=C1)[O-])N=CC=C2.C1=CC2=C(C(=C1)[O-])N=CC=C2.[Ni+2]

Technology Process of Nickel(2+) diquinolin-8-olate

There total 8 articles about Nickel(2+) diquinolin-8-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.7%

8-quinolinol (148-24-3,24804-14-6) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) → nickel(II) 8-hydroxyquinolate (14100-15-3)

Guidance literature:

With ammonium acetate; acetic acid; In water; soln. of Ni(CH3COO)2 and 20% aq. ammonium acetate added to hot soln. of 8-hydroxyquinoline in 1 M acetic acid; ppt. filtered off; washed (boiling water); dried at 100°C;

DOI:10.1134/S0036023606090142

Reference yield: 53.0%

8-quinolinol (148-24-3,24804-14-6) + nickel(II) chloride hexahydrate → nickel(II) 8-hydroxyquinolate (14100-15-3)

Guidance literature:

With potassium hydroxide; In ethanol; Reflux;

DOI:10.13005/ojc/320620

Reference yield:

{Ni(8-C9H6NO)2} * 3 pyridine → nickel(II) 8-hydroxyquinolate (14100-15-3)

Guidance literature:

In neat (no solvent); byproducts: pyridine; heating for 5-6 wk to 100°C;;

DOI:10.1021/ja01118a057

upstream raw materials:

8-quinolinol

nickel diacetate

nickel(II)

{Ni(8-C₉H₆NO)2}*2H₂O

Downstream raw materials:

5,10,15,20-tetraphenylporphinatonickel(II)

Refernces

• 1、 Titova, Yu. Yu.,Belykh,Shmidt. "Formation and properties of Ziegler systems based on nickel bis(dimethylglyoximate) in catalysis of hydrogenation reactions". . p. 2413 - 2420. Retrieved 2014.
• 2、 Bailey,A.S. et al.. "". . p. 2579 - 2587. Retrieved 1965.
• 3、 Stary, J.. "". . p. 132 - 149. Retrieved 1963.
• 4、 Gentry, C. H. R.,Sherrington, L. G.. "". . p. 17 - 21. Retrieved 1950.
• 5、 Kolhe Nitin,Jadhav Shridhar,Shaikh Sajid,Takate Sushama,Aware Dinkar. "Nanocrystalline mixed ligand complexes of Cu (II), Ni (II), Co(II) with N, O donor ligands: Synthesis, characterization, and antimicrobial activity". . p. 2999 - 3013. Retrieved 2017/01/09.