1,1-bis(phenylmethylthio)-1-sulfinylmethane

Base Information

• Chemical Name: 1,1-bis(phenylmethylthio)-1-sulfinylmethane
• CAS No.: 188055-10-9
• Molecular Formula: C₁₅H₁₄OS₃
• Molecular Weight: 306.474
• Mol file: 188055-10-9.mol

Synonyms:1,1-bis(phenylmethylthio)-1-sulfinylmethane

Chemical Property of 1,1-bis(phenylmethylthio)-1-sulfinylmethane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1,1-bis(phenylmethylthio)-1-sulfinylmethane

There total 1 articles about 1,1-bis(phenylmethylthio)-1-sulfinylmethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

dibenzyl trithiocarbonate (26504-29-0) → 1,1-bis(phenylmethylthio)-1-sulfinylmethane (188055-10-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 0.333333h;

DOI:10.1016/S0040-4020(96)01071-X

Reference yield:

methyllithium (917-54-4) + 1,1-bis(phenylmethylthio)-1-sulfinylmethane (188055-10-9) → bis(phenylmethylthio)(methylsulfinyl)methane

Guidance literature:

In tetrahydrofuran; diethyl ether; at -78 ℃; for 0.166667h; Yield given;

DOI:10.1016/S0040-4020(96)01071-X

Reference yield:

1,1-bis(phenylmethylthio)-1-sulfinylmethane (188055-10-9) → S-phenylmethyl thioformate (32779-85-4)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran; diethyl ether / 0.17 h / -78 °C

2: 70 percent / 192 h / Ambient temperature

In tetrahydrofuran; diethyl ether;

DOI:10.1016/S0040-4020(96)01071-X

upstream raw materials:

dibenzyl trithiocarbonate

Downstream raw materials:

S-phenylmethyl thioformate

tris(phenylmethylthio)methane

Refernces