p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside

Base Information

• Chemical Name: p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside
• CAS No.: 395072-15-8
• Molecular Formula: C₆₃H₅₀N₂O₁₈
• Molecular Weight: 1123.09
• Mol file: 395072-15-8.mol

Synonyms:p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside

Chemical Property of p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside

There total 11 articles about p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C65H52N2O19 → p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside (395072-15-8)

Guidance literature:

With acetyl chloride; In methanol; dichloromethane; at 0 ℃; for 14h;

DOI:10.1021/ol010257h

Reference yield:

2-[(2S,3R,4R,5S,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-4,5-dihydroxy-2-(4-methoxy-phenoxy)-tetrahydro-pyran-3-yl]-isoindole-1,3-dione → p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside (395072-15-8)

Guidance literature:

Multi-step reaction with 4 steps

1: pyridine / 12 h / 20 °C

2: 0.088 g / H₂SO₄ / methanol / 5 h / 0 °C

3: NIS; 4 Angstroem molecular sieves; TfOH / CH₂Cl₂ / 1 h / 20 °C

4: 8.0 g / AcCl / methanol; CH₂Cl₂ / 14 h / 0 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; sulfuric acid; acetyl chloride; In pyridine; methanol; dichloromethane;

DOI:10.1021/ol010257h

Reference yield:

C41H43NO10Si → p-methoxyphenyl 3,4-di-O-benzoyl-6-O-(3,4-di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-2-deoxy-2-phthalimido-β-D-glucopyranoside (395072-15-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 0.088 g / H₂SO₄ / methanol / 5 h / 0 °C

2: NIS; 4 Angstroem molecular sieves; TfOH / CH₂Cl₂ / 1 h / 20 °C

3: 8.0 g / AcCl / methanol; CH₂Cl₂ / 14 h / 0 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; sulfuric acid; acetyl chloride; In methanol; dichloromethane;

DOI:10.1021/ol010257h

upstream raw materials:

C₄₀H₄₁NO₈SSi

p-Methoxyphenyl 2-deoxy-2-phthalimido-β-D-glucopyranoside

benzoyl chloride

2-((2S,3R,4R,5S,6R)-4,5-Dihydroxy-6-hydroxymethyl-2-phenylsulfanyl-tetrahydro-pyran-3-yl)-isoindole-1,3-dione