Technology Process of C62H82N4O4S2
There total 9 articles about C62H82N4O4S2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
5-bromo-4,4'-dioctyl-2,2'-bithiophene;
With
n-butyllithium;
In
tetrahydrofuran;
at -78 ℃;
for 0.666667h;
With
tributyltin chloride;
In
tetrahydrofuran;
at -78 - 20 ℃;
for 2h;
2,2'-phenyl-{5-[4-bromo-2,5-bis(octyloxy)phenyl]-1,3,4-oxadiazole}phenyl-1,3,4-oxadiazole;
tetrakis(triphenylphosphine) palladium(0);
In
toluene;
at 20 - 100 ℃;
for 49h;
DOI:10.1021/jo0521596
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 70 percent / TMEDA; nBuLi; CuCl2 / -78 - 50 °C
2.1: 76 percent / NBS / CHCl3; acetic acid / 2 h / 0 °C
3.1: nBuLi; Bu3SnCl / tetrahydrofuran / 2.67 h / -78 - 20 °C
3.2: 0.18 g / Pd(PPh3)4 / toluene / 49 h / 20 - 100 °C
With
N-Bromosuccinimide; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; tributyltin chloride; copper dichloride;
In
tetrahydrofuran; chloroform; acetic acid;
DOI:10.1016/j.tetlet.2006.02.001
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 60 percent / nBuLi / tetrahydrofuran / -78 - 20 °C
2.1: 83 percent / NH2NH2*H2O / methanol / 12 h / Heating
3.1: 45 percent / pyridine / tetrahydrofuran / 13 h / 20 - 60 °C
4.1: 73 percent / POCl3 / 8 h / 100 °C
5.1: nBuLi; Bu3SnCl / tetrahydrofuran / 2.67 h / -78 - 20 °C
5.2: 0.18 g / Pd(PPh3)4 / toluene / 49 h / 20 - 100 °C
With
pyridine; n-butyllithium; tributyltin chloride; hydrazine hydrate; trichlorophosphate;
In
tetrahydrofuran; methanol;
DOI:10.1016/j.tetlet.2006.02.001