Stannane, (o-iodobenzoyloxy)tripropyl-

Base Information

• Chemical Name: Stannane, (o-iodobenzoyloxy)tripropyl-
• CAS No.: 73927-94-3
• Molecular Formula: C₁₆H₂₅IO₂Sn
• Molecular Weight: 494.988
• DSSTox Substance ID: DTXSID40224561
• NSC Number: 221677
• Wikidata: Q83103165
• Mol file: 73927-94-3.mol

Synonyms:Stannane, (o-iodobenzoyloxy)tripropyl-;Tripropyltin o-iodobenzoate;(o-Iodobenzoyloxy)tripropylstannane;73927-94-3;Stannane, ((2-iodobenzoyl)oxy)tripropyl-;Stannane, [(2-iodobenzoyl)oxy]tripropyl-;Tin, tripropyl-, o-iodobenzoate;NSC 221677;BRN 3964600;Tin, o-iodobenzoate;DTXSID40224561;NSC221677;NSC-221677

Chemical Property of Stannane, (o-iodobenzoyloxy)tripropyl-

Chemical Property:

• PSA: 26.30000
• LogP: 5.62350
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 495.99213
• Heavy Atom Count: 20
• Complexity: 279

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): A poison. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
• Hazard Codes: A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[Sn](CCC)(CCC)OC(=O)C1=CC=CC=C1I

Technology Process of Stannane, (o-iodobenzoyloxy)tripropyl-

There total 2 articles about Stannane, (o-iodobenzoyloxy)tripropyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2-Iodobenzoic acid (88-67-5) + bis(tri-n-propylstannyl)oxide (1067-29-4) → Tripropylzinno-o-jodobenzoat (73927-94-3)

Guidance literature:

In neat (no solvent); molar ratio (C3H7)3SnOSn(C3H7)3 : acid = 1:2, gentle reflux for 15 min; removal of water formed, recrystn. from hexane;

DOI:10.1021/je60044a054

Reference yield:

→ Tripropylzinno-o-jodobenzoat (73927-94-3)

Guidance literature:

Pr3SnOSnPr3, o-Jodobenzoesaeure;

DOI:10.1021/je60044a054

upstream raw materials:

2-Iodobenzoic acid

bis(tri-n-propylstannyl)oxide