9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

Base Information

Chemical Name:9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine
CAS No.:148943-37-7
Molecular Formula:C₂₇H₃₁N₅O₃Si
Molecular Weight:501.66
Hs Code.:

Synonyms:9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

Suppliers and Price of 9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

Chemical Property:

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Technology Process of 9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

There total 1 articles about 9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 78151-96-9
(desoxy-3-methylidene-3'-β-D-erythro-pentofurannosyl)-9-adenine

: 58479-61-1
tert-butylchlorodiphenylsilane

: 148943-37-7
9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

Guidance literature:: With pyridine; for 18h; Ambient temperature;
DOI:10.1139/v93-027

Reference yield: 93.0%

: 148943-37-7
9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

: 1005-56-7
phenylcarbonochloridothioate

: 9-<5-O-(tert-Butyldiphenylsilyl)-2,3-dideoxy-3-(phenoxycarbonylthio)methyl-β-D-glycero-pent-2-enofuranosyl>adenine

Guidance literature:: With dmap; In acetonitrile; for 18h; Ambient temperature;
DOI:10.1139/v93-027

Reference yield:

: 148943-37-7
9-(5-O-(tert-Butyldiphenylsilyl)-3-deoxy-3-methylene-β-D-erythro-pentofuranosyl)adenine

: 9-(5-O-(tert-Butyldiphenylsilyl)-2,3-dideoxy-3-methyl-β-D-glycero-pent-2-enofuranosyl)adenine

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / DMAP / acetonitrile / 18 h / Ambient temperature

2: 90 percent / AIBN, Bu₃SnH / toluene / 10 h / 100 °C

With dmap; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; acetonitrile;
DOI:10.1139/v93-027