(E)-5-(Phenylthio)pent-2-en-4-inal

Base Information

• Chemical Name: (E)-5-(Phenylthio)pent-2-en-4-inal
• CAS No.: 270918-58-6
• Molecular Formula: C₁₁H₈OS
• Molecular Weight: 188.25
• Mol file: 270918-58-6.mol

Synonyms:(E)-5-(Phenylthio)pent-2-en-4-inal

Chemical Property of (E)-5-(Phenylthio)pent-2-en-4-inal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-5-(Phenylthio)pent-2-en-4-inal

There total 1 articles about (E)-5-(Phenylthio)pent-2-en-4-inal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

β-(E)-iodoacrolein (151160-05-3) + 1-(phenylthio)-2-(trimethylstannyl)ethyne (270918-60-0) → (E)-5-(Phenylthio)pent-2-en-4-inal (270918-58-6)

Guidance literature:

With Et₄(+)Cl(-); tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 14h;

DOI:10.1002/(SICI)1522-2675(20000315)83:3<641::AID-HLCA641>3.0.CO;2-U

Reference yield: 77.0%

(E)-5-(Phenylthio)pent-2-en-4-inal (270918-58-6) → 2-[bis(phenylthio)methyl]furan (71778-41-1)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; at -20 - 20 ℃; for 48.1667h;

DOI:10.1002/1522-2675(20000607)83:6<1191::AID-HLCA1191>3.0.CO;2-X

Reference yield:

(E)-5-(Phenylthio)pent-2-en-4-inal (270918-58-6) → C17H13(2)HOS2

Guidance literature:

With diclazuril; In chloroform-d1; water-d2; at -20 - 20 ℃; for 48.1667h;

DOI:10.1002/1522-2675(20000607)83:6<1191::AID-HLCA1191>3.0.CO;2-X

upstream raw materials:

β-(E)-iodoacrolein

1-(phenylthio)-2-(trimethylstannyl)ethyne

Downstream raw materials:

2-[bis(phenylthio)methyl]furan