[(Z)-hex-3-enyl]-triphenylphosphanium;bromide

Base Information Edit

Chemical Name:[(Z)-hex-3-enyl]-triphenylphosphanium;bromide
CAS No.:21676-05-1
Molecular Formula:Br*C₂₄H₂₆P
Molecular Weight:425.348
Hs Code.:
Mol file:21676-05-1.mol

Synonyms:SCHEMBL5157978

Suppliers and Price of [(Z)-hex-3-enyl]-triphenylphosphanium;bromide

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of [(Z)-hex-3-enyl]-triphenylphosphanium;bromide Edit

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:7
Exact Mass:424.09555
Heavy Atom Count:26
Complexity:335

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCC=CCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
Isomeric SMILES:CC/C=C\CC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]

Technology Process of [(Z)-hex-3-enyl]-triphenylphosphanium;bromide

There total 6 articles about [(Z)-hex-3-enyl]-triphenylphosphanium;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 5009-31-4
(Z)-1-Bromohex-3-ene

: 603-35-0
triphenylphosphine

: 21676-05-1
(3Z)-3-hexenyltriphenylphosphonium bromide

Guidance literature:: at 110 ℃; for 5h;
DOI:10.1002/hlca.19820650204

Reference yield:

: 928-96-1
(Z)-3-Hexen-1-ol

: 21676-05-1
(3Z)-3-hexenyltriphenylphosphonium bromide

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine, Ph₃PBr₂ / acetonitrile / 0 °C

2: acetonitrile / 24 h / Heating

With pyridine; triphenylphosphine dibromide 1:1 addition complex; In acetonitrile;
DOI:10.1021/jo00125a065

Reference yield:

: 1002-28-4
3-hexyn-1-ol

: 21676-05-1
(3Z)-3-hexenyltriphenylphosphonium bromide

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / H₂ / PII Nickel / ethanol / 760 Torr

2: triethylamine / CH₂Cl₂ / 2 h / Ambient temperature

3: lithium bromide / acetone / 12 h / Ambient temperature

4: 2.1 g / benzene / 36 h / Heating

With hydrogen; triethylamine; lithium bromide; PII Nickel; In ethanol; dichloromethane; acetone; benzene;
DOI:10.1016/S0040-4020(01)90314-X