1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene

Base Information

• Chemical Name: 1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene
• CAS No.: 1060978-46-2
• Molecular Formula: C₆₁H₆₇IO₃
• Molecular Weight: 975.106
• Mol file: 1060978-46-2.mol

Synonyms:1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene

Chemical Property of 1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene

There total 1 articles about 1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

4-[tris(4'-tert-butylbiphenyl-4-yl)methyl]phenol (904930-19-4) + 1,2-bis-(2-iodoethoxy)ethane (36839-55-1) → 1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene (1060978-46-2)

Guidance literature:

4-[tris(4'-tert-butylbiphenyl-4-yl)methyl]phenol; With sodium hydride; In tetrahydrofuran; mineral oil; at 20 ℃; for 0.5h; Inert atmosphere;

1,2-bis-(2-iodoethoxy)ethane; In tetrahydrofuran; mineral oil; for 16h; Inert atmosphere;

DOI:10.1021/ja804888b

Reference yield: 76.0%

C98H104N2O6Si2 + 1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene (1060978-46-2) → C208H208N2O12

Guidance literature:

With tetrabutyl ammonium fluoride; caesium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide; at 20 ℃; for 48h; Inert atmosphere;

DOI:10.1021/ja804888b

Reference yield: 56.0%

1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene (1060978-46-2) + C98H88N2O6Si2 → C208H192N2O12

Guidance literature:

C₉₈H₈₈N₂O₆Si₂; With tetrabutyl ammonium fluoride; In tetrahydrofuran; N,N-dimethyl-formamide; at 20 ℃; for 0.0833333h; Inert atmosphere;

1-{tris(4'-tert-butylbiphenyl-4-yl)methyl}-4-{2-[2-(2-iodoethoxy)ethoxy]ethoxy}benzene; With caesium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide; at 20 ℃; for 50h; Inert atmosphere;

DOI:10.1002/chem.201200837

upstream raw materials:

4-[tris(4'-tert-butylbiphenyl-4-yl)methyl]phenol

1,2-bis-(2-iodoethoxy)ethane