trans-[Ru(4-C_.ident.C(C₄H₂S)2CHO)Cl(bis(diphenylphosphino)ethane)2]

Base Information

• Chemical Name: trans-[Ru(4-C_.ident.C(C₄H₂S)2CHO)Cl(bis(diphenylphosphino)ethane)2]
• CAS No.: 791112-78-2
• Molecular Formula: C₆₃H₅₃ClOP₄RuS₂
• Molecular Weight: 1150.66
• Mol file: 791112-78-2.mol

Synonyms:trans-[Ru(4-C_.ident.C(C₄H₂S)2CHO)Cl(bis(diphenylphosphino)ethane)2]

Chemical Property of trans-[Ru(4-C_.ident.C(C₄H₂S)2CHO)Cl(bis(diphenylphosphino)ethane)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Ru(4-C_.ident.C(C₄H₂S)2CHO)Cl(bis(diphenylphosphino)ethane)2]

There total 3 articles about trans-[Ru(4-C_.ident.C(C₄H₂S)2CHO)Cl(bis(diphenylphosphino)ethane)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

[RuCl((C6H5)2PC2H4P(C6H5)2)2(CCH(C4H2S)2CHO)](1+)*CF3SO3(1-)=[RuCl((C6H5)2PC2H4P(C6H5)2)2(CCH(C4H2S)2CHO)][CF3SO3] → trans-[Ru(4-C.ident.C(C4H2S)2CHO)Cl(bis(diphenylphosphino)ethane)2] (791112-78-2)

Guidance literature:

With N(CH₂CH₃)3; In dichloromethane; (inert atm.); addn. of amine to a soln. of ruthenium complex in CH2Cl2, stirring at room temp. for 1 h; washing with water, drying (MgSO4), filtration, evapn., dissolving in CH2Cl2, column chromy. (silica gel, Et2O), evapn., recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1021/om049236s

Reference yield: 65.0%

[RuCl(dppe)2]OTf (253687-41-1) + 5’-ethynyl-[2,2’]bithio-phene-5-carbaldehyde (125972-72-7) → trans-[Ru(4-C.ident.C(C4H2S)2CHO)Cl(bis(diphenylphosphino)ethane)2] (791112-78-2)

Guidance literature:

With triethylamine; In dichloromethane; room temp., 20 h; Et3N added, room temp. 1 h;

DOI:10.1021/jp048794h

Reference yield:

[RuCl(dppe)2]OTf (253687-41-1) + 5’-ethynyl-[2,2’]bithio-phene-5-carbaldehyde (125972-72-7) → [RuCl((CH2P(C6H5)2)2)2(CC(C4H2S)2CHO)] (791112-78-2)

Guidance literature:

With triethylamine; In dichloromethane; Ru compd. with S compd. at room temp. for 20h, triethylamine at room temp. for 1 h;

DOI:10.1103/PhysRevB.71.035119

upstream raw materials:

[RuCl(dppe)2]OTf

5’-ethynyl-[2,2’]bithio-phene-5-carbaldehyde