Rh₂(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3

Base Information

• Chemical Name: Rh₂(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3
• CAS No.: 1300026-19-0
• Molecular Formula: C₃₃H₄₉F₂₄N₅O₈P₄Rh₂
• Molecular Weight: 1429.45
• Mol file: 1300026-19-0.mol

Synonyms:Rh₂(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3

Chemical Property of Rh₂(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh₂(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3

There total 1 articles about Rh₂(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.2%

bis(pentamethylcyclopentadienyl)cobalt(II) (74507-62-3) + tert-butylisonitrile (119072-55-8,7188-38-7) + Rh2(0,II)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)2Cl2 → decamethylcobalticinium chloride (75936-28-6) + Rh2(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3 (1300026-19-0)

Guidance literature:

In tetrahydrofuran; (N2); dissolving a mixt. of Rh complex and isonitrile in THF, addn. to asoln. of Co complex in THF, stirring at room temp. for 3 h; filtration through glass wool, evapn. in vac., dissolving in Et2O/hexanes, concn. in vac., suspn. in hexanes at -20°C overnight, decantation, drying in vac.; elem. anal.;

DOI:10.1021/ic2005248

Reference yield: 82.0%

Rh2(0,0)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3 (1300026-19-0) + p-toluenesulfonic acid monohydrate (6192-52-5) → [Rh2(I,I)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3(μ-H)](p-toluenesulfonate) (1300026-25-8)

Guidance literature:

In acetonitrile; (N2); dropwise addn. of frozen-thawed soln. of acid in acetonitrile to afrozen soln. of Rh complex in acetonitrile, warming to room temp., stir ring for 1 h; evapn. in vac., trituration with Et2O, cooling to -20°C overnight, decantation, drying in vac.; elem. anal.;

DOI:10.1021/ic2005248

upstream raw materials:

bis(pentamethylcyclopentadienyl)cobalt(II)

tert-butylisonitrile

Downstream raw materials:

[Rh2(I,I)(bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine)2(tert-butylisocyanide)3(μ-H)](p-toluenesulfonate)