C₂₆H₃₇NO₆Si

Base Information

• Chemical Name: C₂₆H₃₇NO₆Si
• CAS No.: 1315158-70-3
• Molecular Formula: C₂₆H₃₇NO₆Si
• Molecular Weight: 487.668
• Mol file: 1315158-70-3.mol

Synonyms:C₂₆H₃₇NO₆Si

Chemical Property of C₂₆H₃₇NO₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₆H₃₇NO₆Si

There total 7 articles about C₂₆H₃₇NO₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

C26H35NO4Si (1315158-41-8) → C26H37NO6Si (1315158-70-3)

Guidance literature:

With osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; In acetone; for 24h; diastereoselective reaction;

DOI:10.1016/j.tetlet.2011.05.103

Reference yield:

tert-butyl (2S,3R)-3-(tert-butyldiphenylsilyloxy)-1-hydroxypent-4-en-2-ylcarbamate (1020409-56-6) → C26H37NO6Si (1315158-70-3)

Guidance literature:

Multi-step reaction with 4 steps

1: Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

2: 3 h / -78 - -20 °C

3: Grubbs catalyst first generation / dichloromethane / 12 h / 20 °C

4: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone / 24 h

With Grubbs catalyst first generation; osmium(VIII) oxide; water; Dess-Martin periodane; 4-methylmorpholine N-oxide; In dichloromethane; acetone;

DOI:10.1016/j.tetlet.2011.05.103

Reference yield:

C28H39NO4Si (1315158-35-0) → C26H37NO6Si (1315158-70-3)

Guidance literature:

Multi-step reaction with 2 steps

1: Grubbs catalyst first generation / dichloromethane / 12 h / 20 °C

2: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone / 24 h

With Grubbs catalyst first generation; osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; In dichloromethane; acetone;

DOI:10.1016/j.tetlet.2011.05.103

upstream raw materials:

tert-butyl (2S,3R)-3-(tert-butyldiphenylsilyloxy)-1-hydroxypent-4-en-2-ylcarbamate

C₂₆H₃₅NO₄Si

C₂₈H₃₉NO₄Si

tert-butyl (S)-4-[(R)-1-(tert-butyldiphenylsilyloxy)allyl]-2,2-dimethyloxazolidine-3-carboxylate