dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate

Base Information

Chemical Name:dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate
CAS No.:125877-58-9
Molecular Formula:C₂₃H₂₈N₂O₆
Molecular Weight:428.485
Hs Code.:

Synonyms:dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate

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Chemical Property of dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate

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Technology Process of dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate

There total 7 articles about dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 125877-57-8
dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>hept-5-ene-2,3-dicarboxylate

: 125877-58-9
dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate

Guidance literature:: With potassium diazodicarboxylate; acetic acid; In dichloromethane; at 0 ℃; for 1.5h;
DOI:10.1021/jo00296a035

Reference yield:

: 125877-52-3
6-((tert-butyldimethylsilyl)oxy)-2-methylenehexan-1-ol

: 125877-58-9
dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate

Guidance literature:: Multi-step reaction with 6 steps

1: 96 percent / 4-(dimethylamino)pyridine, pyridine / CH₂Cl₂ / 1 h / Ambient temperature

2: 96 percent / HF / acetonitrile / 2.5 h / Ambient temperature

3: 85 percent / pyridinium chlorochromate (PCC), Celite / CH₂Cl₂ / 2 h / Ambient temperature

4: 91 percent / Et₂NH / methanol / 2.5 h / Ambient temperature

5: 2.4 g / CH₂Cl₂ / 8 h / 4 °C

6: 1.8 g / dipotassium azodicarboxylate, glacial acetic acid / CH₂Cl₂ / 1.5 h / 0 °C

With pyridine; dmap; Celite; hydrogen fluoride; potassium diazodicarboxylate; acetic acid; diethylamine; pyridinium chlorochromate; In methanol; dichloromethane; acetonitrile;
DOI:10.1021/jo00296a035

Reference yield:

: 125877-54-5
1-(benzoyloxy)-2-methylidenehexan-6-ol

: 125877-58-9
dimethyl 2,3-diaza-7-(5'-((benzoyloxy)methyl)hex-5'-enylidene)bicyclo<2.2.1>heptane-2,3-dicarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / pyridinium chlorochromate (PCC), Celite / CH₂Cl₂ / 2 h / Ambient temperature

2: 91 percent / Et₂NH / methanol / 2.5 h / Ambient temperature

3: 2.4 g / CH₂Cl₂ / 8 h / 4 °C

4: 1.8 g / dipotassium azodicarboxylate, glacial acetic acid / CH₂Cl₂ / 1.5 h / 0 °C

With Celite; potassium diazodicarboxylate; acetic acid; diethylamine; pyridinium chlorochromate; In methanol; dichloromethane;
DOI:10.1021/jo00296a035