p-(methoxycarbonyl)phenylmercuric chloride

Base Information

• Chemical Name: p-(methoxycarbonyl)phenylmercuric chloride
• CAS No.: 20883-45-8
• Molecular Formula: C₈H₇HgO₂*Cl
• Molecular Weight: 371.185
• Mol file: 20883-45-8.mol

Synonyms:p-(methoxycarbonyl)phenylmercuric chloride

Chemical Property of p-(methoxycarbonyl)phenylmercuric chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-(methoxycarbonyl)phenylmercuric chloride

There total 3 articles about p-(methoxycarbonyl)phenylmercuric chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

methyl 4-tri-n-butylstannylbenzoate (91734-76-8) + mercury dichloride → 4-methoxycarbonyl-phenylmercury (1+); chloride (20883-45-8)

Guidance literature:

In ethanol;

DOI:10.1007/BF01141722

Reference yield: 79.0%

p-(methoxycarbonyl)phenylmercuric acetate (42497-76-7) → p-(methoxycarbonyl)phenylmercuric chloride (20883-45-8)

Guidance literature:

With potassium chloride; In tetrahydrofuran; to a suspn. of Hg-acetate in THF was added a KCl-soln. and stirred at room temp. for 1.5 h; the product was filtered off and washed with hexane;

DOI:10.1016/0022-328X(89)87048-2

Reference yield:

→ 4-methoxycarbonyl-phenylmercury (1+); chloride (20883-45-8)

Guidance literature:

4-Chlormercuri-benzoesaeure, MeOH, H2SO4;

DOI:10.1021/ja01022a034

upstream raw materials:

methyl 4-tri-n-butylstannylbenzoate

p-(methoxycarbonyl)phenylmercuric acetate

Downstream raw materials:

4-(1-methylethenyl)benzoic acid methyl ester

methyl 4-allylbenzoate

methyl (E)-4-(prop-1-en-1-yl)benzoate

HHgC₆H₄CO₂CH₃