2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one

Base Information

Chemical Name:2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one
CAS No.:139714-68-4
Molecular Formula:C₁₉H₁₆O₅
Molecular Weight:324.333
Hs Code.:

Synonyms:2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one

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Chemical Property of 2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one

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Technology Process of 2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one

There total 7 articles about 2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 139714-66-2,139714-67-3
[(4R,5S)-5-Benzo[1,3]dioxol-5-yl-4-(methoxy-phenyl-methoxymethyl)-4,5-dihydro-furan-2-yloxy]-trimethyl-silane

: 139714-68-4
2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one

Guidance literature:: With titanium tetrachloride; In dichloromethane; at -78 ℃; for 3h;

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 139714-68-4
2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one

Guidance literature:: Multi-step reaction with 5 steps

1: ZnCl₂, Et₃N / CH₂Cl₂

2: 86 percent / borane, dimethyl sulfide / tetrahydrofuran / 0 °C

3: 92 percent / Et₃N / CH₂Cl₂ / 0.25 h / 0 °C

4: 1) LDA / 1) THF, -78 deg C, 30 min, 2) rt

5: 27 percent / TiCl₄ / CH₂Cl₂ / 3 h / -78 °C

With dimethylsulfide; borane; titanium tetrachloride; triethylamine; zinc(II) chloride; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 139714-68-4
2-endo-phenyl-6-exo-(3,4-methylenedioxyphenyl)-3,7-dioxabicyclo<3.3.0>octan-8-one

Guidance literature:: Multi-step reaction with 4 steps

1: SOCl₂, acetyl chloride

2: 92 percent / Et₃N / CH₂Cl₂ / 0.25 h / 0 °C

3: 1) LDA / 1) THF, -78 deg C, 30 min, 2) rt

4: 27 percent / TiCl₄ / CH₂Cl₂ / 3 h / -78 °C

With thionyl chloride; titanium tetrachloride; triethylamine; acetyl chloride; lithium diisopropyl amide; In dichloromethane;