[(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate

Base Information

• Chemical Name: [(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate
• CAS No.: 247064-67-1
• Molecular Formula: C₂₇H₂₆N₂PRu*F₆P
• Molecular Weight: 655.525
• Mol file: 247064-67-1.mol

Synonyms:[(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate

Chemical Property of [(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate

There total 1 articles about [(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate + triphenylphosphine (603-35-0) → [(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate (247064-67-1)

Guidance literature:

1 equiv. of phosphine;

DOI:10.1021/om990264y

Reference yield: 96.0%

[(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate (247064-67-1) + triphenyl-arsane (603-32-7) → (C5H5)Ru(P(C6H5)3)(As(C6H5)3)(CH3CN)(1+)*PF6(1-)=[(C5H5)Ru(P(C6H5)3)(As(C6H5)3)(CH3CN)]PF6 (247170-50-9)

Guidance literature:

In acetone; Ar-atmosphere; stirring (room temp., 2 h), evapn.; filtering, washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1021/om990245o

Reference yield: 93.0%

[(cyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium(II)] hexafluorophosphate (247064-67-1) + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → [Ru(C5H5)(η(2):η(2)-C8H12)(PPh3)]PF6 (247170-35-0)

Guidance literature:

In acetone; Ar-atmosphere; stirring (room temp., 1 h); concg., pptn. on Et2O addn., filtering. washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1021/om990245o

upstream raw materials:

triphenylphosphine

Downstream raw materials:

[Ru(C₅H₅)(P(C₆H₅)3)(HC(CH₃)CH(NHC₅H₄N))]⁽¹⁺⁾*PF₆^(1-)=[Ru(C₅H₅)(P(C₆H₅)3)(HC(CH₃)CH(NHC₅H₄N))]PF₆

(C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₅)3)Br⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(CH₂CHCH₂)(P(C₆H₅)3)Br]PF₆

(C₅H₅)Ru(P(C₆H₅)3)(C₅H₅N)(CH₃CN)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Ru(P(C₆H₅)3)(C₅H₅N)(CH₃CN)]PF₆

[RuCp(η3-CHCHCH-CH2PPh2-η2-C6H4)]PF6