C₂₅H₃₅O₈C₆H₁₅Si

Base Information

Chemical Name:C₂₅H₃₅O₈C₆H₁₅Si
CAS No.:312924-37-1
Molecular Formula:C₃₁H₅₀O₈Si
Molecular Weight:578.819
Hs Code.:

C<sub>25</sub>H<sub>35</sub>O<sub>8</sub>C<sub>6</sub>H<sub>15</sub>Si

Synonyms:C₂₅H₃₅O₈C₆H₁₅Si

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Chemical Property of C₂₅H₃₅O₈C₆H₁₅Si

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Technology Process of C₂₅H₃₅O₈C₆H₁₅Si

There total 16 articles about C₂₅H₃₅O₈C₆H₁₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-2-((1R,2S,6R,7S,8R,9R)-9-Benzyloxymethyl-8-methoxymethoxymethyl-4,4-dimethyl-10-oxo-3,5-dioxa-tricyclo[5.2.2.0^2,6]undec-2-yl)-3-(tert-butyl-dimethyl-silanyloxy)-propionaldehyde

: 312924-37-1
C₂₅H₃₅O₈C₆H₁₅Si

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; samarium diiodide; In tetrahydrofuran; at -40 ℃;
DOI:10.1021/ol000290o

Reference yield:

: 312923-90-3
(1S,3R,7R,8S,9R,10S,11S)-9-Benzyloxymethyl-10-hydroxymethyl-11-methyl-7-trimethylsilanyloxy-4-oxa-tricyclo[5.3.1.0^3,8]undecan-5-one

: 312924-37-1
C₂₅H₃₅O₈C₆H₁₅Si

Guidance literature:: Multi-step reaction with 15 steps

1.1: 33 percent / I₂; PhI(OAc)2 / CH₂Cl₂ / 0 °C / Photolysis

2.1: 85 percent / i-Pr₂NEt / CH₂Cl₂ / 20 °C

3.1: O₃ / CH₂Cl₂ / -78 °C

3.2: 89 percent / Ph₃P / CH₂Cl₂ / -78 - 20 °C

4.1: Zn(BH₄)2 / diethyl ether / 0 °C

5.1: tetrabutylammonium fluoride / tetrahydrofuran / 0 °C

6.1: 93 percent / PPTS / acetone / 20 °C

7.1: 86 percent / LHMDS; HMPA / tetrahydrofuran / -78 °C

8.1: O₃ / CH₂Cl₂ / -78 °C

8.2: Ph₃P / CH₂Cl₂ / -78 - 20 °C

9.1: NaBH₄ / methanol / 20 °C

10.1: o-O₂NC₆H₄SeCN; Bu₃P / tetrahydrofuran / -78 - 20 °C

11.1: LiAlH₄ / dioxane / Heating

12.1: 90 percent / Et₃N / CH₂Cl₂ / 20 °C

13.1: 94 percent / TPAP; 4-methylmorpholine N-oxide / acetonitrile / 20 °C

14.1: O₃ / CH₂Cl₂ / -78 °C

14.2: Ph₃P / CH₂Cl₂ / -78 - 20 °C

15.1: SmI₂; HMPA / tetrahydrofuran / -40 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; lithium aluminium tetrahydride; ortho-nitrophenyl selenocyanate; samarium diiodide; tetrapropylammonium perruthennate; zinc(II) tetrahydroborate; tributylphosphine; [bis(acetoxy)iodo]benzene; tetrabutyl ammonium fluoride; iodine; pyridinium p-toluenesulfonate; ozone; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; lithium hexamethyldisilazane; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; dichloromethane; acetone; acetonitrile; 1.1: Dehydrogenation / 2.1: Alkylation / 3.1: ozonation / 3.2: Ring cleavage / 4.1: Reduction / 5.1: Elimination / 6.1: Cyclization / 7.1: Acylation / 8.1: ozonation / 8.2: Ring cleavage / 9.1: Reduction / 10.1: Dehydration / 11.1: Reduction / 12.1: Substitution / 13.1: Oxidation / 14.1: ozonolysis / 14.2: Ring cleavage / 15.1: Cyclization;
DOI:10.1021/ol000290o

Reference yield:

: 312924-35-9
(1S,3R,7S,8S,9R,10R,11R)-9-Benzyloxymethyl-7,11-dihydroxy-10-methoxymethoxymethyl-4-oxa-tricyclo[5.3.1.0^3,8]undecan-5-one

: 312924-37-1
C₂₅H₃₅O₈C₆H₁₅Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: 93 percent / PPTS / acetone / 20 °C

2.1: 86 percent / LHMDS; HMPA / tetrahydrofuran / -78 °C

3.1: O₃ / CH₂Cl₂ / -78 °C

3.2: Ph₃P / CH₂Cl₂ / -78 - 20 °C

4.1: NaBH₄ / methanol / 20 °C

5.1: o-O₂NC₆H₄SeCN; Bu₃P / tetrahydrofuran / -78 - 20 °C

6.1: LiAlH₄ / dioxane / Heating

7.1: 90 percent / Et₃N / CH₂Cl₂ / 20 °C

8.1: 94 percent / TPAP; 4-methylmorpholine N-oxide / acetonitrile / 20 °C

9.1: O₃ / CH₂Cl₂ / -78 °C

9.2: Ph₃P / CH₂Cl₂ / -78 - 20 °C

10.1: SmI₂; HMPA / tetrahydrofuran / -40 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; lithium aluminium tetrahydride; ortho-nitrophenyl selenocyanate; samarium diiodide; tetrapropylammonium perruthennate; tributylphosphine; pyridinium p-toluenesulfonate; ozone; 4-methylmorpholine N-oxide; triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; acetone; acetonitrile; 1.1: Cyclization / 2.1: Acylation / 3.1: ozonation / 3.2: Ring cleavage / 4.1: Reduction / 5.1: Dehydration / 6.1: Reduction / 7.1: Substitution / 8.1: Oxidation / 9.1: ozonolysis / 9.2: Ring cleavage / 10.1: Cyclization;
DOI:10.1021/ol000290o