2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

Base Information

Chemical Name:2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol
CAS No.:191678-09-8
Molecular Formula:C₄₀H₄₄O₈Si
Molecular Weight:680.87
Hs Code.:

Synonyms:2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

Suppliers and Price of 2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

There total 13 articles about 2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 672-13-9
2-hydroxy-5-methoxybenzaldehyde

: 191678-09-8
2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

Guidance literature:: Multi-step reaction with 7 steps

1: 90 percent / imidazole / tetrahydrofuran / 25 °C

2: 93 percent / m-CPBA / ethyl acetate / 25 °C

3: 61 percent / NaH / tetrahydrofuran / 25 °C

4: 75 percent / t-BuLi / tetrahydrofuran / 25 °C

5: 84 percent / concd. HCl / methanol / 0 °C

6: 63 percent / DDQ / benzene / Heating

7: 1.) t-BuOK/BuLi; 2.) BuLi / 1.) THF, -78 deg C; 2.) THF, -78 deg C

With 1H-imidazole; hydrogenchloride; n-butyllithium; potassium tert-butylate; tert.-butyl lithium; sodium hydride; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; ethyl acetate; benzene;
DOI:10.1016/S0040-4039(97)00927-1

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 191678-09-8
2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

Guidance literature:: Multi-step reaction with 6 steps

1: 86 percent / tetrahydrofuran / -78 °C

2: 60 percent / PCC / CH₂Cl₂ / 25 °C

3: 43 percent / p-TsOH / benzene / Heating

4: 73 percent / LiAlH₄ / diethyl ether / 25 °C

5: 58 percent / PCC / CH₂Cl₂ / 25 °C

6: 1.) t-BuOK/BuLi; 2.) BuLi / 1.) THF, -78 deg C; 2.) THF, -78 deg C

With lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; toluene-4-sulfonic acid; pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; dichloromethane; benzene;
DOI:10.1016/S0040-4039(97)00927-1

Reference yield:

: 34023-63-7
ethyl 3-(benzo[d][1,3]dioxol-5-yl)-3-hydroxypropanoate

: 191678-09-8
2-(2-Benzo[1,3]dioxol-5-yl-[1,3]dioxolan-2-yl)-1-[8-(tert-butyl-diphenyl-silanyloxy)-5-methoxy-2,2-dimethyl-2H-chromen-6-yl]-ethanol

Guidance literature:: Multi-step reaction with 5 steps

1: 60 percent / PCC / CH₂Cl₂ / 25 °C

2: 43 percent / p-TsOH / benzene / Heating

3: 73 percent / LiAlH₄ / diethyl ether / 25 °C

4: 58 percent / PCC / CH₂Cl₂ / 25 °C

5: 1.) t-BuOK/BuLi; 2.) BuLi / 1.) THF, -78 deg C; 2.) THF, -78 deg C

With lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; toluene-4-sulfonic acid; pyridinium chlorochromate; In diethyl ether; dichloromethane; benzene;
DOI:10.1016/S0040-4039(97)00927-1