2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester

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Chemical Name:2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester
CAS No.:858127-21-6
Molecular Formula:C₃₅H₃₄F₃NO₅
Molecular Weight:605.654
Hs Code.:

Synonyms:2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester

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Chemical Property of 2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester

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Technology Process of 2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester

There total 1 articles about 2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 61881-19-4
2,2,2-trifluoro-N-phenyl-acetimidoyl chloride

: 162118-38-9
(3S,4R,5R,6S)-3,4,5-tris(benzyloxy)-6-methyltetrahydro-2H-pyran-2-ol

: 858127-21-6
2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester

Guidance literature:: With sodium hydride; In dichloromethane; at 0 ℃; for 3h;
DOI:10.1021/jo050301x

Reference yield: 82.0%

: 858127-21-6
2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester

: 1418181-43-7
N,N'-bis(4-O-acetyl-1-O-allyl-6-O-benzyl-2,3-N,O-carbonyl-2-deoxy-α-D-glucopyranos-2-yl)urea

: 1418181-44-8
N,N'-bis[(4-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-1-O-allyl-6-O-benzyl-2,3-N,O-carbonyl-2-deoxy-α-D-glucopyranos-2-y)l]urea

Guidance literature:: 2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester; N,N'-bis(4-O-acetyl-1-O-allyl-6-O-benzyl-2,3-N,O-carbonyl-2-deoxy-α-D-glucopyranos-2-yl)urea; In tetrahydrofuran; dichloromethane; toluene; at -30 ℃; for 0.25h; Molecular sieve; Inert atmosphere;

With trimethylsilyl trifluoromethanesulfonate; In tetrahydrofuran; dichloromethane; toluene; at -30 ℃; for 1.5h; Molecular sieve; Inert atmosphere;
DOI:10.1016/j.tet.2012.12.005

Reference yield: 78.0%

: 858127-21-6
2,2,2-Trifluoro-N-phenyl-acetimidic acid (2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester

: 410524-30-0
ethyl [(2Z,3R)-3-(1-hydroxyethyl)-4-oxoazetidin-2-ylidene]acetate

: [(S)-4-Oxo-3-[(R)-1-((2R,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-ethyl]-azetidin-(2Z)-ylidene]-acetic acid ethyl ester

Guidance literature:: With 4 A molecular sieve; ytterbium(III) triflate; In 1,4-dioxane; diethyl ether; dichloromethane; at -30 - 20 ℃;
DOI:10.1002/ejoc.200500665