Ru(CH₃)(CO)2[C₅H₄NCHNCH(CH₃)2][P(C₆H₅)3]⁽¹⁺⁾*I^(1-)=[Ru(CH₃)(CO)2(C₅H₄NCHNCH(CH₃)2)(P(C₆H₅)3)]I

Base Information

• Chemical Name: Ru(CH₃)(CO)2[C₅H₄NCHNCH(CH₃)2][P(C₆H₅)3]⁽¹⁺⁾*I^(1-)=[Ru(CH₃)(CO)2(C₅H₄NCHNCH(CH₃)2)(P(C₆H₅)3)]I
• CAS No.: 157699-18-8
• Molecular Formula: C₃₀H₃₀N₂O₂PRu*I
• Molecular Weight: 709.529
• Mol file: 157699-18-8.mol

Synonyms:Ru(CH₃)(CO)2[C₅H₄NCHNCH(CH₃)2][P(C₆H₅)3]⁽¹⁺⁾*I^(1-)=[Ru(CH₃)(CO)2(C₅H₄NCHNCH(CH₃)2)(P(C₆H₅)3)]I

Chemical Property of Ru(CH₃)(CO)2[C₅H₄NCHNCH(CH₃)2][P(C₆H₅)3]⁽¹⁺⁾*I^(1-)=[Ru(CH₃)(CO)2(C₅H₄NCHNCH(CH₃)2)(P(C₆H₅)3)]I

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(CH₃)(CO)2[C₅H₄NCHNCH(CH₃)2][P(C₆H₅)3]⁽¹⁺⁾*I^(1-)=[Ru(CH₃)(CO)2(C₅H₄NCHNCH(CH₃)2)(P(C₆H₅)3)]I

There total 4 articles about Ru(CH₃)(CO)2[C₅H₄NCHNCH(CH₃)2][P(C₆H₅)3]⁽¹⁺⁾*I^(1-)=[Ru(CH₃)(CO)2(C₅H₄NCHNCH(CH₃)2)(P(C₆H₅)3)]I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

Ru(CH3)I(CO)2[C5H4NCHNCH(CH3)2] (144345-88-0,213926-71-7) → Ru[C(O)CH3]I(CO)2[C5H4NCHNCH(CH3)2] (157741-63-4) + Ru2(CO)4[P(CH3)2C6H5]2[P(C6H5)3]2Cl2 (157699-32-6) + Ru(CH3)(CO)2[C5H4NCHNCH(CH3)2][P(C6H5)3](1+)*I(1-)=[Ru(CH3)(CO)2(C5H4NCHNCH(CH3)2)(P(C6H5)3)]I (157699-18-8)

Guidance literature:

With PPh₃; Ru(CO)4(P(CH₃)2C₆H₅); In chloroform-d1; under N2; react. of Ru-complexes and PPh3 in CDCl3 at 45°C for 17 h;

DOI:10.1021/om00020a046

Reference yield: 10.0%

Ru(CH3)I(CO)2[C5H4NCHNCH(CH3)2] (144345-88-0,213926-71-7) → Ru(CH3)(CO)2[C5H4NCHNCH(CH3)2][P(C6H5)3](1+)*I(1-)=[Ru(CH3)(CO)2(C5H4NCHNCH(CH3)2)(P(C6H5)3)]I (157699-18-8)

Guidance literature:

With P(C₆H₅)3; In chloroform-d1; under N2; Ru-complex and excess PPh3 dissolved in CDCl3, heated to 45°C for 2 h (equil. react.); not isolated, react. monitored by 1H- and 31P-NMR spect.;

DOI:10.1021/om00020a046

Reference yield:

Ru(CO)3(i-Pr-Pyca) → Ru(CH3)(CO)2[C5H4NCHNCH(CH3)2][P(C6H5)3](1+)*I(1-)=[Ru(CH3)(CO)2(C5H4NCHNCH(CH3)2)(P(C6H5)3)]I (157699-18-8)

Guidance literature:

Multi-step reaction with 2 steps

1: CH₃I / not given

2: P(C₆H₅)3 / chloroform-d1

With CH₃I; P(C₆H₅)3; In chloroform-d1;

DOI:10.1021/om00020a046

upstream raw materials:

Ru(CH₃)I(CO)2[C₅H₄NCHNCH(CH₃)2]

Ru[C(O)CH₃]I(CO)2[C₅H₄NCHNCH(CH₃)2]