1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene

Base Information

Chemical Name:1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene
CAS No.:104329-44-4
Molecular Formula:C₁₅H₂₆O₂Si
Molecular Weight:266.456
Hs Code.:

Synonyms:1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene

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Technology Process of 1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene

There total 3 articles about 1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 624-67-9
Propargylic aldehyde

: 179815-45-3
2-methyl-5-<(tert-butyldimethylsilyl)oxy>-1,3-pentadiene

: 104329-44-4
1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene

Guidance literature:: In benzene; at 120 ℃;
DOI:10.1016/S0040-4039(00)83999-4

Reference yield:

: 13369-24-9
(E)-ethyl 4-methylpenta-2,4-dienoate

: 104329-44-4
1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene

Guidance literature:: Multi-step reaction with 3 steps

1: LiAlH₄ / diethyl ether

2: 100 percent / 4-(dimethylamino)pyridine, Et₃N / CH₂Cl₂ / Ambient temperature

3: 98 percent / hydroquinone / benzene / 24 h / 110 - 120 °C

With dmap; lithium aluminium tetrahydride; triethylamine; hydroquinone; In diethyl ether; dichloromethane; benzene;
DOI:10.1021/ja961071u

Reference yield:

: 67065-89-8
(2E)-4-methylpenta-2,4-dien-1-ol

: 104329-44-4
1-formyl-6-<((tert-butyldimethylsilyl)oxy)methyl>-4-methyl-1,4-cyclohexadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / 4-(dimethylamino)pyridine, Et₃N / CH₂Cl₂ / Ambient temperature

2: 98 percent / hydroquinone / benzene / 24 h / 110 - 120 °C

With dmap; triethylamine; hydroquinone; In dichloromethane; benzene;
DOI:10.1021/ja961071u