[1-(4-bromophenyl)allyl]dimethylphenylsilane

Base Information

• Chemical Name: [1-(4-bromophenyl)allyl]dimethylphenylsilane
• CAS No.: 1214913-12-8
• Molecular Formula: C₁₇H₁₉BrSi
• Molecular Weight: 331.327
• Mol file: 1214913-12-8.mol

Synonyms:[1-(4-bromophenyl)allyl]dimethylphenylsilane

Chemical Property of [1-(4-bromophenyl)allyl]dimethylphenylsilane

Chemical Property:

Purity/Quality:

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Technology Process of [1-(4-bromophenyl)allyl]dimethylphenylsilane

There total 3 articles about [1-(4-bromophenyl)allyl]dimethylphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(E)-1-bromo-4-(3-chloroprop-1-en-1-yl)benzene (104293-07-4) + dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane (185990-03-8) → [1-(4-bromophenyl)allyl]dimethylphenylsilane (1214913-12-8)

Guidance literature:

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane; With sodium methylate; copper(l) cyanide; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;

(E)-1-bromo-4-(3-chloroprop-1-en-1-yl)benzene; In tetrahydrofuran; at -78 ℃; regioselective reaction; Inert atmosphere;

DOI:10.1002/anie.201004658

Reference yield:

(E)-1-bromo-4-(3-chloroprop-1-en-1-yl)benzene (104293-07-4) + phenyldimethylsilyl chloride (768-33-2) → [1-(4-bromophenyl)allyl]dimethylphenylsilane (1214913-12-8)

Guidance literature:

phenyldimethylsilyl chloride; With lithium; In tetrahydrofuran; at 0 ℃; for 5h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; diethyl ether; at 0 ℃;

(E)-1-bromo-4-(3-chloroprop-1-en-1-yl)benzene; Further stages;

DOI:10.1039/b920793g

Reference yield:

1-(4-bromophenyl)-1-propen-3-yl bromide (96090-12-9,124854-99-5) + phenyldimethylsilyl chloride (768-33-2) → [1-(4-bromophenyl)allyl]dimethylphenylsilane (1214913-12-8) + C17H19BrSi (1214913-16-2)

Guidance literature:

phenyldimethylsilyl chloride; With lithium; In tetrahydrofuran; at 0 ℃; for 5h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; diethyl ether; at 0 ℃;

1-(4-bromophenyl)-1-propen-3-yl bromide; Further stages;

DOI:10.1039/b920793g

upstream raw materials:

1-(4-bromophenyl)-1-propen-3-yl bromide

phenyldimethylsilyl chloride

(E)-1-bromo-4-(3-chloroprop-1-en-1-yl)benzene

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane