2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

Base Information

Chemical Name:2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole
CAS No.:1578258-35-1
Molecular Formula:C₄₀H₂₇N₅O₂
Molecular Weight:609.687
Hs Code.:

Synonyms:2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

Suppliers and Price of 2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

There total 4 articles about 2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 1451070-74-8
2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

: 586-78-7
para-nitrophenyl bromide

: 1578258-35-1
2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

: 1578258-41-9
2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3,6-bis(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

Guidance literature:: With PdCl(C₃H₅)(1,4-bis(diphenylphosphino)butane); potassium acetate; In N,N-dimethyl acetamide; at 150 ℃; for 72h; Schlenk technique; Inert atmosphere;
DOI:10.1021/jo5002643

Reference yield:

: 106-49-0,12221-03-3
p-toluidine

: 1578258-35-1
2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

: 1578258-41-9
2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3,6-bis(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

Guidance literature:: Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / acetic acid / 0.5 h / 90 °C

2: acetic acid / 3 h / 90 °C

3: potassium acetate; PdCl(C₃H₅)(1,4-bis(diphenylphosphino)butane) / N,N-dimethyl acetamide / 72 h / 150 °C / Schlenk technique; Inert atmosphere

With PdCl(C₃H₅)(1,4-bis(diphenylphosphino)butane); potassium acetate; toluene-4-sulfonic acid; In N,N-dimethyl acetamide; acetic acid;
DOI:10.1021/jo5002643

Reference yield:

: 105-07-7
4-cyanobenzaldehyde

: 1578258-35-1
2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3-(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

: 1578258-41-9
2,5-bis(4-cyanophenyl)-1,4-bis(4-methylphenyl)-3,6-bis(4-nitrophenyl)-1,4-dihydropyrrolo[3,2-b]pyrrole

Guidance literature:: Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / acetic acid / 0.5 h / 90 °C

2: acetic acid / 3 h / 90 °C

3: potassium acetate; PdCl(C₃H₅)(1,4-bis(diphenylphosphino)butane) / N,N-dimethyl acetamide / 72 h / 150 °C / Schlenk technique; Inert atmosphere

With PdCl(C₃H₅)(1,4-bis(diphenylphosphino)butane); potassium acetate; toluene-4-sulfonic acid; In N,N-dimethyl acetamide; acetic acid;
DOI:10.1021/jo5002643